Fe-MOR and Fe-FER as catalysts for abatement of N2O with CH4: in situ UV-vis DRS and operando FTIR study
Maria Cristina Campa
1
,
Daniela Pietrogiacomi
2
,
Carlotta Catracchia
2
,
Simone Morpurgo
2
,
Joanna Elżbieta Olszówka
3
,
Kinga Mlekodaj
3
,
Mariia Lemishka
3, 4
,
Jiri Dedecek
3
,
J. Dědeˇek
3
,
Agnieszka Kornas
3
,
Edyta Tabor
3
1
2
Publication type: Journal Article
Publication date: 2024-03-01
scimago Q1
wos Q1
SJR: 5.180
CiteScore: 38.4
Impact factor: 21.1
ISSN: 09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
The catalytic reduction of N2O with CH4 in absence or in presence of O2 (CRN2O or SCRN2O) and H2O (hydrothermal conditions) was studied on Fe-MOR and Fe-FER catalysts with similar Al distribution and iron-loading. In N2O decomposition and SCRN2O Fe-FER catalysts were more active than Fe-MOR, whereas in CRN2O the catalysts exhibited similar activity. In situ FTIR and UV-vis spectroscopies of thermally activated catalysts revealed that Fe(II) species are better stabilized in FER than in MOR topology. In the presence of CH4, Fe(III)-oxo species were reduced to Fe(II) in both zeolites and became active sites for the CRN2O process. In SCRN2O the presence of O2 decreased the activity of Fe-MOR due to a partial re-oxidation of the active sites. The addition of H2O to the feed caused a poor and reversible deactivation. Operando FTIR experiments provided insights into the reaction pathways and suggested formaldehyde and formate surface species as intermediates.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
ACS Catalysis
2 publications, 8%
|
|
|
Environmental Science & Technology
2 publications, 8%
|
|
|
Journal of Physical Chemistry C
1 publication, 4%
|
|
|
Ceramics International
1 publication, 4%
|
|
|
ACS Omega
1 publication, 4%
|
|
|
Materials Today Communications
1 publication, 4%
|
|
|
Chemical Society Reviews
1 publication, 4%
|
|
|
Mendeleev Communications
1 publication, 4%
|
|
|
Green Chemical Engineering
1 publication, 4%
|
|
|
ChemPhysMater
1 publication, 4%
|
|
|
Chinese Journal of Catalysis
1 publication, 4%
|
|
|
Catalysis Science and Technology
1 publication, 4%
|
|
|
ACS applied materials & interfaces
1 publication, 4%
|
|
|
International Journal of Hydrogen Energy
1 publication, 4%
|
|
|
Dalton Transactions
1 publication, 4%
|
|
|
Journal of the American Chemical Society
1 publication, 4%
|
|
|
Microporous and Mesoporous Materials
1 publication, 4%
|
|
|
Materials Advances
1 publication, 4%
|
|
|
Angewandte Chemie
1 publication, 4%
|
|
|
Angewandte Chemie - International Edition
1 publication, 4%
|
|
|
Chemical Reviews
1 publication, 4%
|
|
|
Environmental Science: Nano
1 publication, 4%
|
|
|
Applied Surface Science
1 publication, 4%
|
|
|
1
2
|
Publishers
|
1
2
3
4
5
6
7
8
9
|
|
|
American Chemical Society (ACS)
9 publications, 36%
|
|
|
Elsevier
8 publications, 32%
|
|
|
Royal Society of Chemistry (RSC)
5 publications, 20%
|
|
|
Wiley
2 publications, 8%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 4%
|
|
|
1
2
3
4
5
6
7
8
9
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
25
Total citations:
25
Citations from 2025:
16
(64%)
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Campa M. C. et al. Fe-MOR and Fe-FER as catalysts for abatement of N2O with CH4: in situ UV-vis DRS and operando FTIR study // Applied Catalysis B: Environmental. 2024. Vol. 342. p. 123360.
GOST all authors (up to 50)
Copy
Campa M. C., Pietrogiacomi D., Catracchia C., Morpurgo S., Olszówka J. E., Mlekodaj K., Lemishka M., Dedecek J., Dědeˇek J., Kornas A., Tabor E. Fe-MOR and Fe-FER as catalysts for abatement of N2O with CH4: in situ UV-vis DRS and operando FTIR study // Applied Catalysis B: Environmental. 2024. Vol. 342. p. 123360.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.apcatb.2023.123360
UR - https://linkinghub.elsevier.com/retrieve/pii/S0926337323010032
TI - Fe-MOR and Fe-FER as catalysts for abatement of N2O with CH4: in situ UV-vis DRS and operando FTIR study
T2 - Applied Catalysis B: Environmental
AU - Campa, Maria Cristina
AU - Pietrogiacomi, Daniela
AU - Catracchia, Carlotta
AU - Morpurgo, Simone
AU - Olszówka, Joanna Elżbieta
AU - Mlekodaj, Kinga
AU - Lemishka, Mariia
AU - Dedecek, Jiri
AU - Dědeˇek, J.
AU - Kornas, Agnieszka
AU - Tabor, Edyta
PY - 2024
DA - 2024/03/01
PB - Elsevier
SP - 123360
VL - 342
SN - 0926-3373
SN - 1873-3883
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2024_Campa,
author = {Maria Cristina Campa and Daniela Pietrogiacomi and Carlotta Catracchia and Simone Morpurgo and Joanna Elżbieta Olszówka and Kinga Mlekodaj and Mariia Lemishka and Jiri Dedecek and J. Dědeˇek and Agnieszka Kornas and Edyta Tabor},
title = {Fe-MOR and Fe-FER as catalysts for abatement of N2O with CH4: in situ UV-vis DRS and operando FTIR study},
journal = {Applied Catalysis B: Environmental},
year = {2024},
volume = {342},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0926337323010032},
pages = {123360},
doi = {10.1016/j.apcatb.2023.123360}
}