Open Access
Monomeric and dimeric magnesium mono-BHT complexes as effective ROP catalysts
Тип публикации: Journal Article
Дата публикации: 2016-12-01
scimago Q1
wos Q2
SJR: 0.811
CiteScore: 7.9
Impact factor: 4.3
ISSN: 15667367
General Chemistry
Catalysis
Process Chemistry and Technology
Краткое описание
Abstract Monomeric and dimeric mono-BHT magnesium complexes [BuMg(μ-BHT)]2 (2), BuMg(BHT)(THF)2 (3), and [(μ-EtO)Mg(BHT)(THF)]2 (4) were synthesized starting from 2,6-di-tert-butyl-4-methylphenol (butylated hydroxytoluene, BHT-H) and Bu2Mg. The molecular structures of compounds 2–4 were established using X-ray diffraction. Being activated by alcohol (monomeric 3) or thermally (dimeric 4), mono-BHT complexes demonstrate high catalytic activity in the ring-opening polymerization of e-caprolactone (e-CL), ω-pentadecalactone (ω-PDL) and ( dl )-lactide. In the latter case, a heterotactic polymer with a Pr of up to 87% is formed. Analysis of the terminal groups of poly(e-CL), which was obtained using 3/BnOH, indicated that the ROP initiator possesses an alkoxy-magnesium nature.
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ГОСТ
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Nifant'ev I. E. et al. Monomeric and dimeric magnesium mono-BHT complexes as effective ROP catalysts // Catalysis Communications. 2016. Vol. 87. pp. 106-111.
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Nifant'ev I. E., Shlyakhtin A. V., Tavtorkin A. N., Ivchenko P. V., Borisov R. S., Churakov A. V. Monomeric and dimeric magnesium mono-BHT complexes as effective ROP catalysts // Catalysis Communications. 2016. Vol. 87. pp. 106-111.
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TY - JOUR
DO - 10.1016/j.catcom.2016.09.018
UR - https://linkinghub.elsevier.com/retrieve/pii/S1566736716303351
TI - Monomeric and dimeric magnesium mono-BHT complexes as effective ROP catalysts
T2 - Catalysis Communications
AU - Nifant'ev, Ilya E.
AU - Shlyakhtin, Andrey V.
AU - Tavtorkin, Alexander N.
AU - Ivchenko, Pavel V
AU - Borisov, Roman S.
AU - Churakov, Andrei V.
PY - 2016
DA - 2016/12/01
PB - Elsevier
SP - 106-111
VL - 87
SN - 1566-7367
ER -
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BibTex (до 50 авторов)
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@article{2016_Nifant'ev,
author = {Ilya E. Nifant'ev and Andrey V. Shlyakhtin and Alexander N. Tavtorkin and Pavel V Ivchenko and Roman S. Borisov and Andrei V. Churakov},
title = {Monomeric and dimeric magnesium mono-BHT complexes as effective ROP catalysts},
journal = {Catalysis Communications},
year = {2016},
volume = {87},
publisher = {Elsevier},
month = {dec},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1566736716303351},
pages = {106--111},
doi = {10.1016/j.catcom.2016.09.018}
}