Open Access
Open access
Elsevier
Catalysis Communications
,  volume 119 ,  pages 144-152

Diastereoselective synthesis of functionally substituted alkene dimers and oligomers, catalysed by chiral zirconocenes

Publication type: Journal Article
Publication date: 2019-01-01
Elsevier
scimago Q1
wos Q2
SJR: 0.811
CiteScore: 7.9
Impact factor: 4.3
ISSN: 15667367
General Chemistry
Catalysis
Process Chemistry and Technology
Abstract
Abstract The research addresses the reaction of terminal alkenes and propene with AlR3 (R = Me, Et) in the presence of chiral Zr complexes, rac-[Y(η5-C9H10)2]ZrCl2 (Y = C2H4, SiMe2) or (NMI)2ZrCl2 (NMI- η5–neomenthylindenyl), and methylaluminoxane. The effect of reaction conditions, catalyst and trialkylalane structure on the substrate conversion and the reaction chemo- and stereoselectivity has been studied. The reaction predominantly goes via the stage of alkene methyl(ethyl)zirconation with subsequent introduction of substrate molecules into the Zr-C bond. As a result, a diastereoselective one-pot method for the synthesis of functionally substituted linear terminal alkene dimers and propene oligomers was developed.
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Kovyazin P. V., Abdullin I. N., Parfenova L. V. Diastereoselective synthesis of functionally substituted alkene dimers and oligomers, catalysed by chiral zirconocenes // Catalysis Communications. 2019. Vol. 119. pp. 144-152.
GOST all authors (up to 50) Copy
Kovyazin P. V., Abdullin I. N., Parfenova L. V. Diastereoselective synthesis of functionally substituted alkene dimers and oligomers, catalysed by chiral zirconocenes // Catalysis Communications. 2019. Vol. 119. pp. 144-152.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.catcom.2018.10.032
UR - https://doi.org/10.1016/j.catcom.2018.10.032
TI - Diastereoselective synthesis of functionally substituted alkene dimers and oligomers, catalysed by chiral zirconocenes
T2 - Catalysis Communications
AU - Kovyazin, Pavel V
AU - Abdullin, Ilgiz N
AU - Parfenova, Lyudmila V.
PY - 2019
DA - 2019/01/01
PB - Elsevier
SP - 144-152
VL - 119
SN - 1566-7367
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Kovyazin,
author = {Pavel V Kovyazin and Ilgiz N Abdullin and Lyudmila V. Parfenova},
title = {Diastereoselective synthesis of functionally substituted alkene dimers and oligomers, catalysed by chiral zirconocenes},
journal = {Catalysis Communications},
year = {2019},
volume = {119},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.catcom.2018.10.032},
pages = {144--152},
doi = {10.1016/j.catcom.2018.10.032}
}