Experimental procedure and statistical data treatment for the kinetic study of selective hydrodechlorination of 1,2-dichloroethane into ethylene over a Pd-Ag sol–gel catalyst
Sophie L Pirard
1
,
Jean-Paul Pirard
1
,
Georges Heyen
2
,
Jean-Paul Schoebrechts
3
,
Benoît Heinrichs
1
3
Solvay S.A., Technology Research and Procurement Intellectual Assets Management, rue de Ransbeek 310, B-1120 Brussels, Belgium
|
Publication type: Journal Article
Publication date: 2011-10-01
scimago Q1
wos Q1
SJR: 2.696
CiteScore: 20.6
Impact factor: 13.2
ISSN: 13858947, 18733212
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Environmental Chemistry
Abstract
The kinetics of selective hydrodechlorination of 1,2-dichloroethane into ethylene over a Pd-Ag/SiO 2 catalyst was studied using an a priori experimental design with five independent variables—temperature and partial pressures of 1,2-dichloroethane, hydrogen, ethylene and hydrogen chloride. A Langmuir–Hinshelwood model including two types of active site and the 1,2-dichloroethane adsorption as the rate-determining step was found to fit correctly with experimental data, according to the analysis of variance and the analysis of pondered residuals. The study allowed for catalytic deactivation. The rigorous experimental and statistical approach followed to carry out such a kinetic study is explained in detail.
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11
Total citations:
11
Citations from 2024:
1
(9.09%)
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GOST
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Pirard S. L. et al. Experimental procedure and statistical data treatment for the kinetic study of selective hydrodechlorination of 1,2-dichloroethane into ethylene over a Pd-Ag sol–gel catalyst // Chemical Engineering Journal. 2011. Vol. 173. No. 3. pp. 801-812.
GOST all authors (up to 50)
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Pirard S. L., Pirard J., Heyen G., Schoebrechts J., Heinrichs B. Experimental procedure and statistical data treatment for the kinetic study of selective hydrodechlorination of 1,2-dichloroethane into ethylene over a Pd-Ag sol–gel catalyst // Chemical Engineering Journal. 2011. Vol. 173. No. 3. pp. 801-812.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.cej.2011.07.002
UR - https://doi.org/10.1016/j.cej.2011.07.002
TI - Experimental procedure and statistical data treatment for the kinetic study of selective hydrodechlorination of 1,2-dichloroethane into ethylene over a Pd-Ag sol–gel catalyst
T2 - Chemical Engineering Journal
AU - Pirard, Sophie L
AU - Pirard, Jean-Paul
AU - Heyen, Georges
AU - Schoebrechts, Jean-Paul
AU - Heinrichs, Benoît
PY - 2011
DA - 2011/10/01
PB - Elsevier
SP - 801-812
IS - 3
VL - 173
SN - 1385-8947
SN - 1873-3212
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Pirard,
author = {Sophie L Pirard and Jean-Paul Pirard and Georges Heyen and Jean-Paul Schoebrechts and Benoît Heinrichs},
title = {Experimental procedure and statistical data treatment for the kinetic study of selective hydrodechlorination of 1,2-dichloroethane into ethylene over a Pd-Ag sol–gel catalyst},
journal = {Chemical Engineering Journal},
year = {2011},
volume = {173},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.cej.2011.07.002},
number = {3},
pages = {801--812},
doi = {10.1016/j.cej.2011.07.002}
}
Cite this
MLA
Copy
Pirard, Sophie L., et al. “Experimental procedure and statistical data treatment for the kinetic study of selective hydrodechlorination of 1,2-dichloroethane into ethylene over a Pd-Ag sol–gel catalyst.” Chemical Engineering Journal, vol. 173, no. 3, Oct. 2011, pp. 801-812. https://doi.org/10.1016/j.cej.2011.07.002.