Chemical Engineering Journal, volume 470, pages 144144
Linear furoxan assemblies incorporating nitrobifuroxan scaffold: En route to new high-performance energetic materials
Publication type: Journal Article
Publication date: 2023-08-01
Journal:
Chemical Engineering Journal
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15.1
ISSN: 13858947
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Environmental Chemistry
Abstract
Energetic materials science is undergoing a global renaissance aiming to reach an ideal combination between reliable synthetic strategies, high performance and acceptable molecular stabilities. In this work, design and synthesis of novel energetic non-hydrogen furoxan assemblies has been successfully realized. Fine tunability of molecular composition in a series of furoxan-based materials was achieved by the variation of a number of heterocyclic rings and employing N-oxide regioisomerism strategy. Using this approach, advanced energetic regioisomeric azo-bridged bifuroxan assemblies 6 and 7 as well as 3,4′-dinitro-3′,4-bifuroxan 8 with the excellent overall performance were synthesized. Calculations of Hirshfeld surfaces and molecular electrostatic potentials were conducted to better understand the relationship between the molecular structure and mechanical sensitivity in the synthesized series of energetic materials. It was found, that the supramolecular aggregation of 3,4′-dinitro-3′,4-bifuroxan 8 molecules in crystal is more anisotropic that is commonly believed to be more favorable pattern for the low sensitive substances. All target materials have high densities (1.88–1.95 g cm−3), acceptable thermal stabilities (up to 165 °C), high enthalpies of formation (1.6–2.4 kJ g−1) and positive oxygen balance to CO (up to + 25%). As a result, these compounds exhibit high detonation velocities (9.1–9.5 km s−1), excellent heats of explosion (6.6–7.2 kJ g−1) and combustion performance (Isp = 269–281 s). Therefore, these furoxan-based advanced energetic materials unveil new opportunities in search of next-generation functional organic materials for various applications.
Citations by journals
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Mendeleev Communications
2 publications, 14.29%
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Journal of Organic Chemistry
2 publications, 14.29%
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Chemical Engineering Science
1 publication, 7.14%
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Journal of Chemical Physics
1 publication, 7.14%
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Chemistry - A European Journal
1 publication, 7.14%
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RSC Advances
1 publication, 7.14%
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Energetic Materials Frontiers
1 publication, 7.14%
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Russian Chemical Reviews
1 publication, 7.14%
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Journal of Heterocyclic Chemistry
1 publication, 7.14%
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Chemical Engineering Journal
1 publication, 7.14%
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Russian Chemical Bulletin
1 publication, 7.14%
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International Journal of Molecular Sciences
1 publication, 7.14%
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Citations by publishers
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5
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Elsevier
5 publications, 35.71%
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Wiley
2 publications, 14.29%
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American Chemical Society (ACS)
2 publications, 14.29%
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American Institute of Physics (AIP)
1 publication, 7.14%
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Royal Society of Chemistry (RSC)
1 publication, 7.14%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.14%
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Springer Nature
1 publication, 7.14%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 7.14%
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5
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Larin A. A. et al. Linear furoxan assemblies incorporating nitrobifuroxan scaffold: En route to new high-performance energetic materials // Chemical Engineering Journal. 2023. Vol. 470. p. 144144.
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Larin A. A., Degtyarev D. D., Ananyev I. V., Pivkina A., Fershtat L. L. Linear furoxan assemblies incorporating nitrobifuroxan scaffold: En route to new high-performance energetic materials // Chemical Engineering Journal. 2023. Vol. 470. p. 144144.
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TY - JOUR
DO - 10.1016/j.cej.2023.144144
UR - https://doi.org/10.1016/j.cej.2023.144144
TI - Linear furoxan assemblies incorporating nitrobifuroxan scaffold: En route to new high-performance energetic materials
T2 - Chemical Engineering Journal
AU - Larin, Alexander A
AU - Degtyarev, Daniil D.
AU - Ananyev, Ivan V
AU - Pivkina, Alla
AU - Fershtat, Leonid L.
PY - 2023
DA - 2023/08/01 00:00:00
PB - Elsevier
SP - 144144
VL - 470
SN - 1385-8947
ER -
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@article{2023_Larin,
author = {Alexander A Larin and Daniil D. Degtyarev and Ivan V Ananyev and Alla Pivkina and Leonid L. Fershtat},
title = {Linear furoxan assemblies incorporating nitrobifuroxan scaffold: En route to new high-performance energetic materials},
journal = {Chemical Engineering Journal},
year = {2023},
volume = {470},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.cej.2023.144144},
pages = {144144},
doi = {10.1016/j.cej.2023.144144}
}