Crystal structure and magnetic properties of a thiazyl organic ferromagnet, BBDTA·GaCl4 with Tc=7.0 K
Wataru FUJITA
1
,
Kunio Awaga
2, 3, 4
2
Department of Chemistry, Graduate School of Science
4
Chikusa-ku Nagoya 464-8602 Japan
|
Publication type: Journal Article
Publication date: 2004-04-01
scimago Q2
wos Q2
SJR: 0.546
CiteScore: 5.9
Impact factor: 3.1
ISSN: 00092614, 18734448
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Three polymorphs, labeled α (plates), β (needles), and γ (blocks), of BBDTA(=benzo[1,2-d:4,5-d′]bis[1,3,2]dithiazole) · GaCl4 were obtained as a mixture of three polymorphs, by recrystallization at −23 °C. The γ-phase showed the ferromagnetic ordering at 7.0 K, in contrast to diamagnetic properties of the α- and β-phases. The crystal structure of the γ-phase exhibited a minimal overlap between the singly occupied molecular orbitals of neighboring molecules, in spite of short interatomic S⋯N distances.
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GOST
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FUJITA W. et al. Crystal structure and magnetic properties of a thiazyl organic ferromagnet, BBDTA·GaCl4 with Tc=7.0 K // Chemical Physics Letters. 2004. Vol. 388. No. 1-3. pp. 186-189.
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FUJITA W., Awaga K. Crystal structure and magnetic properties of a thiazyl organic ferromagnet, BBDTA·GaCl4 with Tc=7.0 K // Chemical Physics Letters. 2004. Vol. 388. No. 1-3. pp. 186-189.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.cplett.2004.02.084
UR - https://doi.org/10.1016/j.cplett.2004.02.084
TI - Crystal structure and magnetic properties of a thiazyl organic ferromagnet, BBDTA·GaCl4 with Tc=7.0 K
T2 - Chemical Physics Letters
AU - FUJITA, Wataru
AU - Awaga, Kunio
PY - 2004
DA - 2004/04/01
PB - Elsevier
SP - 186-189
IS - 1-3
VL - 388
SN - 0009-2614
SN - 1873-4448
ER -
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BibTex (up to 50 authors)
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@article{2004_FUJITA,
author = {Wataru FUJITA and Kunio Awaga},
title = {Crystal structure and magnetic properties of a thiazyl organic ferromagnet, BBDTA·GaCl4 with Tc=7.0 K},
journal = {Chemical Physics Letters},
year = {2004},
volume = {388},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.cplett.2004.02.084},
number = {1-3},
pages = {186--189},
doi = {10.1016/j.cplett.2004.02.084}
}
Cite this
MLA
Copy
FUJITA, Wataru, et al. “Crystal structure and magnetic properties of a thiazyl organic ferromagnet, BBDTA·GaCl4 with Tc=7.0 K.” Chemical Physics Letters, vol. 388, no. 1-3, Apr. 2004, pp. 186-189. https://doi.org/10.1016/j.cplett.2004.02.084.
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