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, volume 9 , issue 7-8 , pages 1001-1004

Fullerene peroxides

Liangbing Gan ¹

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Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, Peking University, Beijing 100871, China. |

Publication type: Journal Article

Publication date: 2006-02-07

Cellule MathDoc/Centre Mersenne

Comptes Rendus Chimie

scimago Q3

wos Q4

SJR: 0.209

CiteScore: 2.3

Impact factor: 0.6

ISSN: 16310748, 18781543

DOI: 10.1016/j.crci.2005.11.003

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General Chemistry

General Chemical Engineering

Abstract

t-Butylperoxy radical adds to fullerenes to form a number of stable fullerene mixed peroxides. The reaction follows the stepwise radical addition mechanism, and usually gives a mixture of products with different numbers of ^t-butylperoxo groups attached on the fullerene cage. Sequential para-addition on the hexagons is the dominant addition pattern. The peroxo groups and fullerene carbons around them exhibit facile reactivity towards various Lewis acids and nucleophiles. The fullerene peroxides can be easily separated by normal column chromatography. Single-crystal X-ray analysis confirmed the presence of peroxo groups. .

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Kraevaya Olga

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PhD in Chemistry

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Gan L. Fullerene peroxides // Comptes Rendus Chimie. 2006. Vol. 9. No. 7-8. pp. 1001-1004.

GOST all authors (up to 50) Copy

Gan L. Fullerene peroxides // Comptes Rendus Chimie. 2006. Vol. 9. No. 7-8. pp. 1001-1004.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.crci.2005.11.003

UR - https://comptes-rendus.academie-sciences.fr/chimie/articles/10.1016/j.crci.2005.11.003/

TI - Fullerene peroxides

T2 - Comptes Rendus Chimie

AU - Gan, Liangbing

PY - 2006

DA - 2006/02/07

PB - Cellule MathDoc/Centre Mersenne

SP - 1001-1004

IS - 7-8

VL - 9

SN - 1631-0748

SN - 1878-1543

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2006_Gan,

author = {Liangbing Gan},

title = {Fullerene peroxides},

journal = {Comptes Rendus Chimie},

year = {2006},

volume = {9},

publisher = {Cellule MathDoc/Centre Mersenne},

month = {feb},

url = {https://comptes-rendus.academie-sciences.fr/chimie/articles/10.1016/j.crci.2005.11.003/},

number = {7-8},

pages = {1001--1004},

doi = {10.1016/j.crci.2005.11.003}

}

MLA

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MLA Copy

Gan, Liangbing. “Fullerene peroxides.” Comptes Rendus Chimie, vol. 9, no. 7-8, Feb. 2006, pp. 1001-1004. https://comptes-rendus.academie-sciences.fr/chimie/articles/10.1016/j.crci.2005.11.003/.

Publisher

Cellule MathDoc/Centre Mersenne

Journal

Comptes Rendus Chimie

scimago Q3

wos Q4

SJR

0.209

CiteScore

2.3

Impact factor

0.6

ISSN

16310748 (Print)

18781543 (Electronic)