Ion mobility in Nafion-117 membranes
Publication type: Journal Article
Publication date: 2004-10-01
scimago Q1
wos Q1
SJR: 1.721
CiteScore: 14.3
Impact factor: 9.8
ISSN: 00119164, 18734464
General Chemistry
General Chemical Engineering
General Materials Science
Mechanical Engineering
Water Science and Technology
Abstract
Transport phenomena in Nafion-117 perfluorosulphonic membranes have been studied by different techniques. Membrane electric conductivity has been measured under alternative current as a function of the equilibrating concentrations of MCI (M = Li, Na, K) and HCl solutions. Conductivities were found to increase for lithium and sodium membrane forms and decrease for the potassium form with an electrolyte concentration increase. The obtained data were compared with the results of diffusion permeability, ion-exchange kinetics, 7Li and 35Cl NMR measurements. In all cases permeability increased with electrolyte concentration growth. Diffusion coefficients and transport numbers for different counter- and co-ions were determined. The obtained data are discussed with the use of the two-phase membrane structure model. The selectivity of membrane sorption was found to increase with growth of cation radius.
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147
Total citations:
147
Citations from 2024:
28
(19%)
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GOST
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Sistat P. et al. Ion mobility in Nafion-117 membranes // Desalination. 2004. Vol. 170. No. 1. pp. 49-57.
GOST all authors (up to 50)
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Stenina I. A., Sistat P., Rebrov A., Pourcelly G., Yaroslavtsev A. B. Ion mobility in Nafion-117 membranes // Desalination. 2004. Vol. 170. No. 1. pp. 49-57.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.desal.2004.02.092
UR - https://linkinghub.elsevier.com/retrieve/pii/S0011916404800183
TI - Ion mobility in Nafion-117 membranes
T2 - Desalination
AU - Stenina, Irina A
AU - Sistat, Ph.
AU - Rebrov, A.I.
AU - Pourcelly, Gérald
AU - Yaroslavtsev, A. B.
PY - 2004
DA - 2004/10/01
PB - Elsevier
SP - 49-57
IS - 1
VL - 170
SN - 0011-9164
SN - 1873-4464
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2004_Sistat,
author = {Irina A Stenina and Ph. Sistat and A.I. Rebrov and Gérald Pourcelly and A. B. Yaroslavtsev},
title = {Ion mobility in Nafion-117 membranes},
journal = {Desalination},
year = {2004},
volume = {170},
publisher = {Elsevier},
month = {oct},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0011916404800183},
number = {1},
pages = {49--57},
doi = {10.1016/j.desal.2004.02.092}
}
Cite this
MLA
Copy
Sistat, Ph., et al. “Ion mobility in Nafion-117 membranes.” Desalination, vol. 170, no. 1, Oct. 2004, pp. 49-57. https://linkinghub.elsevier.com/retrieve/pii/S0011916404800183.
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