Quasi-equilibrium voltammetric curves resulting from the existence of two immobile charge carriers within electroactive polymer films
4
Department of Chemistry, State Pedagogical University “A.I. Herzen”, St. Petersburg, Russian Federation
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Publication type: Journal Article
Publication date: 2013-10-01
scimago Q1
wos Q1
SJR: 1.106
CiteScore: 10.6
Impact factor: 5.6
ISSN: 00134686, 18733859
General Chemical Engineering
Electrochemistry
Abstract
Abstract In the paper, we have considered possible causes responsible for the fact that CV-curves of electrodes modified by polymer metal complexes with the Schiff bases possess some shoulders or split into two peaks, while the total electrode process has a one-electron character. This study includes a quantitative analysis of voltammetric responses of electrodes, the modifying films of which contain, beside mobile charge carriers (counter-ions), two kinds of immobile ones. Three cases of polymer films are the object of the corresponding description, namely systems combining such charge carriers formed either independently of each other or due to some conversions between them. The obtained results are in a qualitative agreement with those observed in experimental conditions.
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Malev V. V. et al. Quasi-equilibrium voltammetric curves resulting from the existence of two immobile charge carriers within electroactive polymer films // Electrochimica Acta. 2013. Vol. 108. pp. 313-320.
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Malev V. V., Levin O. V., Timonov A. M. Quasi-equilibrium voltammetric curves resulting from the existence of two immobile charge carriers within electroactive polymer films // Electrochimica Acta. 2013. Vol. 108. pp. 313-320.
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TY - JOUR
DO - 10.1016/j.electacta.2013.06.101
UR - https://doi.org/10.1016/j.electacta.2013.06.101
TI - Quasi-equilibrium voltammetric curves resulting from the existence of two immobile charge carriers within electroactive polymer films
T2 - Electrochimica Acta
AU - Malev, V V
AU - Levin, O. V.
AU - Timonov, A M
PY - 2013
DA - 2013/10/01
PB - Elsevier
SP - 313-320
VL - 108
SN - 0013-4686
SN - 1873-3859
ER -
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@article{2013_Malev,
author = {V V Malev and O. V. Levin and A M Timonov},
title = {Quasi-equilibrium voltammetric curves resulting from the existence of two immobile charge carriers within electroactive polymer films},
journal = {Electrochimica Acta},
year = {2013},
volume = {108},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.electacta.2013.06.101},
pages = {313--320},
doi = {10.1016/j.electacta.2013.06.101}
}
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