volume 150 issue 2-3 pages 155-163

Probing reaction mechanisms in mixed phase TiO2 by EPR

Publication typeJournal Article
Publication date2006-02-01
scimago Q2
wos Q3
SJR0.601
CiteScore3.6
Impact factor1.5
ISSN03682048, 18732526
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Radiation
Abstract
Charge separation processes in mixed phase TiO2 photocatalysts are investigated by electron paramagnetic resonance (EPR) spectroscopy. The mechanisms of interfacial electron transfer, subsequent charge migration and recombination at surface sites, and other interfacial effects on chlorophenol/TiO2 chemistry have been probed. Distorted interfacial sites have been observed and are proposed as catalytically reactive hot spots. This detailed knowledge of charge transfer processes is critical to the nanoscale design of catalysts and subsequent improvement of catalytic efficiency.
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GOST Copy
Hurum D. C. et al. Probing reaction mechanisms in mixed phase TiO2 by EPR // Journal of Electron Spectroscopy and Related Phenomena. 2006. Vol. 150. No. 2-3. pp. 155-163.
GOST all authors (up to 50) Copy
Hurum D. C., Agrios A. G., Crist S. E., Gray K., Rajh T., Thurnauer M. C. Probing reaction mechanisms in mixed phase TiO2 by EPR // Journal of Electron Spectroscopy and Related Phenomena. 2006. Vol. 150. No. 2-3. pp. 155-163.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.elspec.2005.01.294
UR - https://doi.org/10.1016/j.elspec.2005.01.294
TI - Probing reaction mechanisms in mixed phase TiO2 by EPR
T2 - Journal of Electron Spectroscopy and Related Phenomena
AU - Hurum, D C
AU - Agrios, Alexander G.
AU - Crist, S E
AU - Gray, Kimberly
AU - Rajh, Tijana
AU - Thurnauer, M. C.
PY - 2006
DA - 2006/02/01
PB - Elsevier
SP - 155-163
IS - 2-3
VL - 150
SN - 0368-2048
SN - 1873-2526
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2006_Hurum,
author = {D C Hurum and Alexander G. Agrios and S E Crist and Kimberly Gray and Tijana Rajh and M. C. Thurnauer},
title = {Probing reaction mechanisms in mixed phase TiO2 by EPR},
journal = {Journal of Electron Spectroscopy and Related Phenomena},
year = {2006},
volume = {150},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.elspec.2005.01.294},
number = {2-3},
pages = {155--163},
doi = {10.1016/j.elspec.2005.01.294}
}
MLA
Cite this
MLA Copy
Hurum, D. C., et al. “Probing reaction mechanisms in mixed phase TiO2 by EPR.” Journal of Electron Spectroscopy and Related Phenomena, vol. 150, no. 2-3, Feb. 2006, pp. 155-163. https://doi.org/10.1016/j.elspec.2005.01.294.