Inorganica Chimica Acta

, том 363 , издание 14 , страницы 4059-4064

High-temperature spin-crossover in coordination compounds of iron(II) with tris(pyrazol-1-yl)methane

O G Shakirova ¹

L. G. Lavrenova ^{2, 3}

V A Daletsky ¹

E A Shusharina ^{2, 3}

T P Griaznova ⁴

Sergey A. Katsyuba ⁴

Victor V. Syakaev ⁴

V V Skripacheva ⁴

A.R Mustafina ⁴

S. E. Solovieva ⁴

Скрыть аффилиации авторов Показать аффилиации авторов: 4 аффилиации

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva, 3, Novosibirsk 630090, Russia |

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva, 3, Novosibirsk 630090, Russia |

Novosibirsk State University, Pirogov str. 2, Novosibirsk 630090, Russia |

⁴

A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Centre of the Russian Academy of Sciences, Arbuzov str. 8, 420088 Kazan, Russia

Институт органической и физической химии им. А.Е. Арбузова КазНЦ РАН

Казанский научный центр РАН

Тип публикации: Journal Article

Дата публикации: 2010-11-01

Elsevier

Inorganica Chimica Acta

scimago Q3

wos Q2

БС2

SJR: 0.393

CiteScore: 5.5

Impact factor: 3.2

ISSN: 00201693, 18733255

DOI: 10.1016/j.ica.2010.08.013

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

Novel mononuclear Fe(II) complexes of tris(pyrazol-1-yl)methane [Fe{HC(pz)3}2]2+ with SiF 6 2 - and p-sulfonatothiacalix[4]arene (TCAS4−) as counterions were obtained. The compounds were characterized by magnetic susceptibility method, IR and UV–Vis spectroscopy. The structure of [Fe{HC(pz)3}2]SiF6 has been analyzed by single-crystal X-ray diffraction. The 1H NMR spectroscopy measurements of [Fe{HC(pz)3}2]2(TСAS) in aqueous solution reveal the outer sphere inclusion of [Fe{HC(pz)3}2]2+ into the cyclophanic cavity of TCAS4−. The temperature induced spin-crossover 1А1 ⇔ 5Т2, accompanied by thermochromism, has been revealed from the temperature dependence of μeff and IR spectra for both complexes. The comparative analysis of magnetochemical and spectroscopy data elucidates the effect of the cyclophanic counterion on the physico-chemical properties of Fe(II) complex.

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Shakirova O. G. et al. High-temperature spin-crossover in coordination compounds of iron(II) with tris(pyrazol-1-yl)methane // Inorganica Chimica Acta. 2010. Vol. 363. No. 14. pp. 4059-4064.

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Shakirova O. G., Lavrenova L. G., Daletsky V. A., Shusharina E. A., Griaznova T. P., Katsyuba S. A., Syakaev V. V., Skripacheva V. V., Mustafina A., Solovieva S. E. High-temperature spin-crossover in coordination compounds of iron(II) with tris(pyrazol-1-yl)methane // Inorganica Chimica Acta. 2010. Vol. 363. No. 14. pp. 4059-4064.

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TY - JOUR

DO - 10.1016/j.ica.2010.08.013

UR - https://doi.org/10.1016/j.ica.2010.08.013

TI - High-temperature spin-crossover in coordination compounds of iron(II) with tris(pyrazol-1-yl)methane

T2 - Inorganica Chimica Acta

AU - Shakirova, O G

AU - Lavrenova, L. G.

AU - Daletsky, V A

AU - Shusharina, E A

AU - Griaznova, T P

AU - Katsyuba, Sergey A.

AU - Syakaev, Victor V.

AU - Skripacheva, V V

AU - Mustafina, A.R

AU - Solovieva, S. E.

PY - 2010

DA - 2010/11/01

PB - Elsevier

SP - 4059-4064

IS - 14

VL - 363

SN - 0020-1693

SN - 1873-3255

ER -

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@article{2010_Shakirova,

author = {O G Shakirova and L. G. Lavrenova and V A Daletsky and E A Shusharina and T P Griaznova and Sergey A. Katsyuba and Victor V. Syakaev and V V Skripacheva and A.R Mustafina and S. E. Solovieva},

title = {High-temperature spin-crossover in coordination compounds of iron(II) with tris(pyrazol-1-yl)methane},

journal = {Inorganica Chimica Acta},

year = {2010},

volume = {363},

publisher = {Elsevier},

month = {nov},

url = {https://doi.org/10.1016/j.ica.2010.08.013},

number = {14},

pages = {4059--4064},

doi = {10.1016/j.ica.2010.08.013}

}

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Shakirova, O. G., et al. “High-temperature spin-crossover in coordination compounds of iron(II) with tris(pyrazol-1-yl)methane.” Inorganica Chimica Acta, vol. 363, no. 14, Nov. 2010, pp. 4059-4064. https://doi.org/10.1016/j.ica.2010.08.013.