Valence tautomerism in copper coordination chemistry
Publication type: Journal Article
Publication date: 2018-09-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Valence tautomerism in coordination chemistry is currently intensely studied, and several seminal review articles discuss important aspects of its applications in catalysis and material science. This article does not intend to comprehensively review research in this field, but to highlight the quest for new redox-active ligands for the rational design of valence tautomeric copper complexes and the control of the barrier for intramolecular electron-transfer. Redox-active guanidines as emerging new ligands for this purpose are in the focus of the discussion, and are compared to the established oxolene-type ligands that also nature uses.
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Metrics
58
Total citations:
58
Citations from 2025:
7
(12.07%)
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BibTex
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RIS
Copy
TY - JOUR
DO - 10.1016/j.ica.2017.07.069
UR - https://doi.org/10.1016/j.ica.2017.07.069
TI - Valence tautomerism in copper coordination chemistry
T2 - Inorganica Chimica Acta
AU - Himmel, Hans‐Jörg
PY - 2018
DA - 2018/09/01
PB - Elsevier
SP - 56-68
VL - 481
SN - 0020-1693
SN - 1873-3255
ER -
Cite this
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Copy
@article{2018_Himmel,
author = {Hans‐Jörg Himmel},
title = {Valence tautomerism in copper coordination chemistry},
journal = {Inorganica Chimica Acta},
year = {2018},
volume = {481},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.ica.2017.07.069},
pages = {56--68},
doi = {10.1016/j.ica.2017.07.069}
}