Open Access
Controlled synthesis and catalytic properties of supported In–Pd intermetallic compounds
Publication type: Journal Article
Publication date: 2016-08-01
scimago Q1
wos Q1
SJR: 1.558
CiteScore: 10.9
Impact factor: 6.5
ISSN: 00219517, 10902694
Catalysis
Physical and Theoretical Chemistry
Abstract
Abstract DTA/TG/MS measurements were used to investigate the temperature-dependent and successive phase formation of different intermetallic In–Pd compounds by controlled reduction of PdO/In2O3 with hydrogen. Reduction procedures were developed to obtain supported intermetallic InPd and In3Pd2 particles by reactive metal–support interaction (RMSI) without detectable amounts of other compounds. In7Pd3 could only be obtained in admixture with elemental indium due to the direct reduction of the In2O3 support at temperatures above 350 °C. All materials exhibit catalytic activity for methanol steam reforming and exhibit high CO2 selectivities up to 98%. Long-term measurements proved the superior stability of the In–Pd/In2O3 materials in comparison with Cu-based systems over 100 h times on stream with high selectivity.
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98
Total citations:
98
Citations from 2025:
10
(10.2%)
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GOST
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Neumann M. et al. Controlled synthesis and catalytic properties of supported In–Pd intermetallic compounds // Journal of Catalysis. 2016. Vol. 340. pp. 49-59.
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Neumann M., Teschner D., Knop-Gericke A., Reschetilowski W., Armbrüster M. Controlled synthesis and catalytic properties of supported In–Pd intermetallic compounds // Journal of Catalysis. 2016. Vol. 340. pp. 49-59.
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TY - JOUR
DO - 10.1016/j.jcat.2016.05.006
UR - https://doi.org/10.1016/j.jcat.2016.05.006
TI - Controlled synthesis and catalytic properties of supported In–Pd intermetallic compounds
T2 - Journal of Catalysis
AU - Neumann, Matthias
AU - Teschner, D
AU - Knop-Gericke, Axel
AU - Reschetilowski, Wladimir
AU - Armbrüster, Marc
PY - 2016
DA - 2016/08/01
PB - Elsevier
SP - 49-59
VL - 340
SN - 0021-9517
SN - 1090-2694
ER -
Cite this
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Copy
@article{2016_Neumann,
author = {Matthias Neumann and D Teschner and Axel Knop-Gericke and Wladimir Reschetilowski and Marc Armbrüster},
title = {Controlled synthesis and catalytic properties of supported In–Pd intermetallic compounds},
journal = {Journal of Catalysis},
year = {2016},
volume = {340},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.jcat.2016.05.006},
pages = {49--59},
doi = {10.1016/j.jcat.2016.05.006}
}