CO monolayer oxidation on Pt nanoparticles: Further insights into the particle size effects
Publication type: Journal Article
Publication date: 2007-01-01
scimago Q1
wos Q1
SJR: 0.760
CiteScore: 8.1
Impact factor: 4.1
ISSN: 15726657, 18732569
General Chemical Engineering
Analytical Chemistry
Electrochemistry
Abstract
This paper provides further insights into the particle size effects in CO monolayer oxidation. Strong particle size effects are confirmed in the size range from 1.8 to 5 nm. The discrepancies in the literature concerned with the particle size effects in CO monolayer oxidation are reconciled by exploring the influence of the experimental conditions on the stripping voltammograms and chronoamperograms. Evidence supporting the contribution of slow non-electrochemical step to the overall mechanism of CO oxidation is presented. The particle size effects in CO monolayer oxidation are attributed to the size-dependent CO ads + OH ads interaction as well as to the size-dependent CO ads surface diffusion coefficient.
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Metrics
221
Total citations:
221
Citations from 2025:
2
(0.9%)
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GOST
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Maillard F., Savinova E. R., Stimming U. CO monolayer oxidation on Pt nanoparticles: Further insights into the particle size effects // Journal of Electroanalytical Chemistry. 2007. Vol. 599. No. 2. pp. 221-232.
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Maillard F., Savinova E. R., Stimming U. CO monolayer oxidation on Pt nanoparticles: Further insights into the particle size effects // Journal of Electroanalytical Chemistry. 2007. Vol. 599. No. 2. pp. 221-232.
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RIS
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TY - JOUR
DO - 10.1016/j.jelechem.2006.02.024
UR - https://doi.org/10.1016/j.jelechem.2006.02.024
TI - CO monolayer oxidation on Pt nanoparticles: Further insights into the particle size effects
T2 - Journal of Electroanalytical Chemistry
AU - Maillard, Frédéric
AU - Savinova, Elena R.
AU - Stimming, Ulrich
PY - 2007
DA - 2007/01/01
PB - Elsevier
SP - 221-232
IS - 2
VL - 599
SN - 1572-6657
SN - 1873-2569
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_Maillard,
author = {Frédéric Maillard and Elena R. Savinova and Ulrich Stimming},
title = {CO monolayer oxidation on Pt nanoparticles: Further insights into the particle size effects},
journal = {Journal of Electroanalytical Chemistry},
year = {2007},
volume = {599},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.jelechem.2006.02.024},
number = {2},
pages = {221--232},
doi = {10.1016/j.jelechem.2006.02.024}
}
Cite this
MLA
Copy
Maillard, Frédéric, et al. “CO monolayer oxidation on Pt nanoparticles: Further insights into the particle size effects.” Journal of Electroanalytical Chemistry, vol. 599, no. 2, Jan. 2007, pp. 221-232. https://doi.org/10.1016/j.jelechem.2006.02.024.