Complete electrochemical dechlorination of chlorobenzenes in the presence of naphthalene mediator
Publication type: Journal Article
Publication date: 2007-09-01
scimago Q1
wos Q1
SJR: 3.078
CiteScore: 24.6
Impact factor: 11.3
ISSN: 03043894, 18733336
PubMed ID:
17669589
Environmental Chemistry
Environmental Engineering
Health, Toxicology and Mutagenesis
Pollution
Waste Management and Disposal
Abstract
Electrochemical dechlorination of chlorobenzene in organic solutions was studied. Electrolysis of chlorobenzene in acetonitrile solution in a one-compartment cell fitted with a platinum cathode and a zinc anode at 60 mA/cm 2 and 0 °C was found to be the optimum conditions, which gave complete dechlorination of chlorobenzene. However, similar result could not be achieved when applying these conditions to 1,3-dichlorobenzene and 1,2,4-trichlorobenzene. We found that the use of naphthalene which reacted as a mediator in the appropriate system could accelerate the reduction and gave complete dechlorination of those chlorobenzenes. Moreover, in the presence of naphthalene the reaction time could be shortened by half compared to dechlorination in the absence of naphthalene.
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26
Total citations:
26
Citations from 2025:
1
(3.85%)
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MLA
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GOST
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Jalil A. A. et al. Complete electrochemical dechlorination of chlorobenzenes in the presence of naphthalene mediator // Journal of Hazardous Materials. 2007. Vol. 148. No. 1-2. pp. 1-5.
GOST all authors (up to 50)
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Jalil A. A., Panjang N. F. A., Akhbar S., Sundang M., Tajuddin N., Triwahyono S. Complete electrochemical dechlorination of chlorobenzenes in the presence of naphthalene mediator // Journal of Hazardous Materials. 2007. Vol. 148. No. 1-2. pp. 1-5.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jhazmat.2007.06.024
UR - https://doi.org/10.1016/j.jhazmat.2007.06.024
TI - Complete electrochemical dechlorination of chlorobenzenes in the presence of naphthalene mediator
T2 - Journal of Hazardous Materials
AU - Jalil, Aishah A
AU - Panjang, N Fatimah A
AU - Akhbar, Suffiyana
AU - Sundang, Murni
AU - Tajuddin, Norhuda
AU - Triwahyono, Sugeng
PY - 2007
DA - 2007/09/01
PB - Elsevier
SP - 1-5
IS - 1-2
VL - 148
PMID - 17669589
SN - 0304-3894
SN - 1873-3336
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2007_Jalil,
author = {Aishah A Jalil and N Fatimah A Panjang and Suffiyana Akhbar and Murni Sundang and Norhuda Tajuddin and Sugeng Triwahyono},
title = {Complete electrochemical dechlorination of chlorobenzenes in the presence of naphthalene mediator},
journal = {Journal of Hazardous Materials},
year = {2007},
volume = {148},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.jhazmat.2007.06.024},
number = {1-2},
pages = {1--5},
doi = {10.1016/j.jhazmat.2007.06.024}
}
Cite this
MLA
Copy
Jalil, Aishah A., et al. “Complete electrochemical dechlorination of chlorobenzenes in the presence of naphthalene mediator.” Journal of Hazardous Materials, vol. 148, no. 1-2, Sep. 2007, pp. 1-5. https://doi.org/10.1016/j.jhazmat.2007.06.024.