том 691 издание 13 страницы 3060-3064

Oxidative addition of an imidazolium cation to an anionic gallium(I) N-heterocyclic carbene analogue: Synthesis and characterisation of novel gallium hydride complexes

Тип публикацииJournal Article
Дата публикации2006-06-01
scimago Q3
wos Q2
БС2
SJR0.385
CiteScore4.1
Impact factor2.4
ISSN0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The reactions of N-heterocyclic carbenes and imidazolium salts towards an anionic gallium(I) heterocycle, [:Ga{[N(Ar)C(H)]2}]−, Ar = C 6 H 3 Pr 2 i - 2 , 6 , have been studied. No reactions with N-heterocyclic carbenes were observed, though the reaction of the gallium heterocycle with the imidazolium salt, [HC{N(Mes)C(H)}2]Cl, IMesHCl, Mes = C6H2Me3-2,4,6, led to oxidative insertion of the Ga(I) centre into the imidazolium C–H bond and formation of the gallium hydride complex, [HGa{[N(Ar)C(H)]2}(IMes)]. When this reaction was carried out in the presence of traces of water, partial hydrolysis of [HGa{[N(Ar)C(H)]2}(IMes)] resulted in the formation of the hydroxy-bridged, anionic gallium hydride complex, [{HGa[N(Ar)C(H)]2}2OH][(IMes)2H]. Both compounds have been spectroscopically and structurally characterised.
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ГОСТ |
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Jones C. et al. Oxidative addition of an imidazolium cation to an anionic gallium(I) N-heterocyclic carbene analogue: Synthesis and characterisation of novel gallium hydride complexes // Journal of Organometallic Chemistry. 2006. Vol. 691. No. 13. pp. 3060-3064.
ГОСТ со всеми авторами (до 50) Скопировать
Jones C., Mills D. S., Rose R. P. Oxidative addition of an imidazolium cation to an anionic gallium(I) N-heterocyclic carbene analogue: Synthesis and characterisation of novel gallium hydride complexes // Journal of Organometallic Chemistry. 2006. Vol. 691. No. 13. pp. 3060-3064.
RIS |
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TY - JOUR
DO - 10.1016/j.jorganchem.2006.03.018
UR - https://doi.org/10.1016/j.jorganchem.2006.03.018
TI - Oxidative addition of an imidazolium cation to an anionic gallium(I) N-heterocyclic carbene analogue: Synthesis and characterisation of novel gallium hydride complexes
T2 - Journal of Organometallic Chemistry
AU - Jones, Cameron
AU - Mills, David S.
AU - Rose, Richard P
PY - 2006
DA - 2006/06/01
PB - Elsevier
SP - 3060-3064
IS - 13
VL - 691
SN - 0022-328X
SN - 1872-8561
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2006_Jones,
author = {Cameron Jones and David S. Mills and Richard P Rose},
title = {Oxidative addition of an imidazolium cation to an anionic gallium(I) N-heterocyclic carbene analogue: Synthesis and characterisation of novel gallium hydride complexes},
journal = {Journal of Organometallic Chemistry},
year = {2006},
volume = {691},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.jorganchem.2006.03.018},
number = {13},
pages = {3060--3064},
doi = {10.1016/j.jorganchem.2006.03.018}
}
MLA
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Jones, Cameron, et al. “Oxidative addition of an imidazolium cation to an anionic gallium(I) N-heterocyclic carbene analogue: Synthesis and characterisation of novel gallium hydride complexes.” Journal of Organometallic Chemistry, vol. 691, no. 13, Jun. 2006, pp. 3060-3064. https://doi.org/10.1016/j.jorganchem.2006.03.018.