The transannular interaction germanium-nitrogen in germocanes: The influence of substituents
Jörg Sundermeyer
2
,
Anastasia A. Selina
1
,
Sergey S. Karlov
1
,
Judith A. Howard
4
,
Yuri F. Oprunenko
1
,
Mikhail Yu. Antipin
5
,
Galina S. Zaitseva
1
1
Publication type: Journal Article
Publication date: 2006-12-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The reaction of RN(CH2CH2OH)CHR1CR2R3OH (1–8) with a stoichiometric amount of tetrachloro(bromo)germane leads to the corresponding RN(CH2CH2O)(CHR1CR2R3O)GeHal2 (9–21). Difluorenylgermocane 22 was prepared by treatment of diethoxydifluorenylgermane with N-methyldiethanolamine. Different dialkanolamines were found to be successive precursors of dimethylgermocanes, RN(CH2CH2O)(CHR1CR2R3O)GeMe2 (23–26). The chemical properties of simple and easy to access germocanes RN(CH2CH2O)2GeX2 [X = OH, Br (28), Cl (29)] were studied and the difluoro (27), haloalkoxy (30–32), and dialkoxy (33, 34) derivatives were prepared. The structures of the compounds 16, 20–22, and 26 were confirmed by X-ray diffraction and the structural features in solution of 23 and 26 were studied by NMR spectroscopy (NOEs). The relationship between the nature of substituents at different positions of the germocane skeleton and the strength of the intramolecular Ge ← N bond is discussed.
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Citations from 2024:
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Lermontova E. K. et al. The transannular interaction germanium-nitrogen in germocanes: The influence of substituents // Journal of Organometallic Chemistry. 2006. Vol. 691. No. 26. pp. 5710-5724.
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Lermontova E. K., Sundermeyer J., Selina A. A., Karlov S. S., Churakov A. V., Howard J. A., Oprunenko Y. F., Antipin M. Y., Zaitseva G. S. The transannular interaction germanium-nitrogen in germocanes: The influence of substituents // Journal of Organometallic Chemistry. 2006. Vol. 691. No. 26. pp. 5710-5724.
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TY - JOUR
DO - 10.1016/j.jorganchem.2006.08.011
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X06005869
TI - The transannular interaction germanium-nitrogen in germocanes: The influence of substituents
T2 - Journal of Organometallic Chemistry
AU - Lermontova, Elmira Kh.
AU - Sundermeyer, Jörg
AU - Selina, Anastasia A.
AU - Karlov, Sergey S.
AU - Churakov, Andrei V.
AU - Howard, Judith A.
AU - Oprunenko, Yuri F.
AU - Antipin, Mikhail Yu.
AU - Zaitseva, Galina S.
PY - 2006
DA - 2006/12/01
PB - Elsevier
SP - 5710-5724
IS - 26
VL - 691
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2006_Lermontova,
author = {Elmira Kh. Lermontova and Jörg Sundermeyer and Anastasia A. Selina and Sergey S. Karlov and Andrei V. Churakov and Judith A. Howard and Yuri F. Oprunenko and Mikhail Yu. Antipin and Galina S. Zaitseva},
title = {The transannular interaction germanium-nitrogen in germocanes: The influence of substituents},
journal = {Journal of Organometallic Chemistry},
year = {2006},
volume = {691},
publisher = {Elsevier},
month = {dec},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X06005869},
number = {26},
pages = {5710--5724},
doi = {10.1016/j.jorganchem.2006.08.011}
}
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MLA
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Lermontova, Elmira Kh., et al. “The transannular interaction germanium-nitrogen in germocanes: The influence of substituents.” Journal of Organometallic Chemistry, vol. 691, no. 26, Dec. 2006, pp. 5710-5724. https://linkinghub.elsevier.com/retrieve/pii/S0022328X06005869.
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