Journal of Organometallic Chemistry

, volume 692 , issue 16 , pages 3424-3429

New effective reagent [Cp2ZrH2·ClAlEt2]2 for alkene hydrometallation

Lyudmila V. Parfenova ¹

Rushana F Vildanova ¹

Svetlana V Pechatkina ¹

Leonard M. Khalilov ¹

Usein M Dzhemilev ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075 Ufa, Prospect Oktyabrya, 141, Russian Federation |

Publication type: Journal Article

Publication date: 2007-07-01

Elsevier

Journal of Organometallic Chemistry

scimago Q3

wos Q2

SJR: 0.385

CiteScore: 4.1

Impact factor: 2.4

ISSN: 0022328X, 18728561

DOI: 10.1016/j.jorganchem.2007.04.007

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Materials Chemistry

Organic Chemistry

Biochemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

New bimetallic complex [Cp2ZrH2 · ClAlEt2]2 (1) was synthesized, and its reactivity in hydrometallation reaction with the following alkenes was studied: hept-1-ene, okt-1-ene, α-methylstyrene, (1S)-β-pinene, (+)-camphene. Complex 1 shows the highest reactivity among the other known Al,Zr-bimetallic complexes: [Cp2ZrH2 · ClAlBui2]2 (2), [Cp2ZrH2 · AlEt3]2 (3), [Cp2ZrH2 · AlBui3]2 (4) and [Cp2ZrH2 · HAlBui2] (5) as well as organoaluminium compounds (OAC): iBu2AlH, iBu3Al and iBu2AlCl in presence of Zr catalysts. Chlorine containing complexes 1 and 2 appear to be more effective in alkene hydrometallation, and relative hydrometallation rates are (1S)-β-pinene ⩽ (+)-camphene

Found

10 citations

Parfenova Lyudmila

🥼 🤝

DSc in Chemistry, associate professor

109 publications, 1 037 citations, 8 reviews

h-index: 17

Institute of Petrochemistry and Catalysis of the Ufa Federal Research Center of the Russian Academy of Sciences

Research interests

Asymmetric metal complex catalysis

Regenerative materials

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Parfenova L. V. et al. New effective reagent [Cp2ZrH2·ClAlEt2]2 for alkene hydrometallation // Journal of Organometallic Chemistry. 2007. Vol. 692. No. 16. pp. 3424-3429.

GOST all authors (up to 50) Copy

Parfenova L. V., Vildanova R. F., Pechatkina S. V., Khalilov L. M., Dzhemilev U. M. New effective reagent [Cp2ZrH2·ClAlEt2]2 for alkene hydrometallation // Journal of Organometallic Chemistry. 2007. Vol. 692. No. 16. pp. 3424-3429.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.jorganchem.2007.04.007

UR - https://doi.org/10.1016/j.jorganchem.2007.04.007

TI - New effective reagent [Cp2ZrH2·ClAlEt2]2 for alkene hydrometallation

T2 - Journal of Organometallic Chemistry

AU - Parfenova, Lyudmila V.

AU - Vildanova, Rushana F

AU - Pechatkina, Svetlana V

AU - Khalilov, Leonard M.

AU - Dzhemilev, Usein M

PY - 2007

DA - 2007/07/01

PB - Elsevier

SP - 3424-3429

IS - 16

VL - 692

SN - 0022-328X

SN - 1872-8561

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2007_Parfenova,

author = {Lyudmila V. Parfenova and Rushana F Vildanova and Svetlana V Pechatkina and Leonard M. Khalilov and Usein M Dzhemilev},

title = {New effective reagent [Cp2ZrH2·ClAlEt2]2 for alkene hydrometallation},

journal = {Journal of Organometallic Chemistry},

year = {2007},

volume = {692},

publisher = {Elsevier},

month = {jul},

url = {https://doi.org/10.1016/j.jorganchem.2007.04.007},

number = {16},

pages = {3424--3429},

doi = {10.1016/j.jorganchem.2007.04.007}

}

MLA

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Parfenova, Lyudmila V., et al. “New effective reagent [Cp2ZrH2·ClAlEt2]2 for alkene hydrometallation.” Journal of Organometallic Chemistry, vol. 692, no. 16, Jul. 2007, pp. 3424-3429. https://doi.org/10.1016/j.jorganchem.2007.04.007.