, volume 694 , issue 23 , pages 3725-3731

On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes

Lyudmila V. Parfenova ¹

Vener Z Gabdrakhmanov ¹

Leonard M. Khalilov ¹

Usein M Dzhemilev ¹

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Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075 Ufa, Prospect Oktyabrya, 141, Russian Federation |

Publication type: Journal Article

Publication date: 2009-11-01

Elsevier

Journal of Organometallic Chemistry

scimago Q3

wos Q2

SJR: 0.385

CiteScore: 4.1

Impact factor: 2.4

ISSN: 0022328X, 18728561

DOI: 10.1016/j.jorganchem.2009.07.037

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Materials Chemistry

Organic Chemistry

Biochemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

The influence of the organoaluminium compound nature, Zr π-ligand environment, solvent type and reagent ratio on the chemoselectivity of reactions of trialkylalanes (AlMe 3 , AlEt 3 ) with alkenes, catalyzed with L 2 ZrCl 2 [L = Cp, Cp′ (Cp′-η 5 -C 5 H 4 CH 3 ), Cp ∗ (Cp ∗ -η 5 -C 5 (CH 3 ) 5 ), Ind (indenyl), Flu (fluorenyl)] has been studied. It is shown that in the case of AlMe 3 , the hydro- and carboalumination products, and alkene dimers are formed. The catalytic reaction of AlEt 3 with the olefins yields aluminacyclopentanes altogether with the hydro- and carboalumination products, and the dimers. A probable reaction mechanism has been proposed.

Found

10 citations

Parfenova Lyudmila

🥼 🤝

DSc in Chemistry, associate professor

109 publications, 1 037 citations, 8 reviews

h-index: 17

Institute of Petrochemistry and Catalysis of the Ufa Federal Research Center of the Russian Academy of Sciences

Research interests

Asymmetric metal complex catalysis

Regenerative materials

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Parfenova L. V. et al. On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes // Journal of Organometallic Chemistry. 2009. Vol. 694. No. 23. pp. 3725-3731.

GOST all authors (up to 50) Copy

Parfenova L. V., Gabdrakhmanov V. Z., Khalilov L. M., Dzhemilev U. M. On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes // Journal of Organometallic Chemistry. 2009. Vol. 694. No. 23. pp. 3725-3731.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.jorganchem.2009.07.037

UR - https://doi.org/10.1016/j.jorganchem.2009.07.037

TI - On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes

T2 - Journal of Organometallic Chemistry

AU - Parfenova, Lyudmila V.

AU - Gabdrakhmanov, Vener Z

AU - Khalilov, Leonard M.

AU - Dzhemilev, Usein M

PY - 2009

DA - 2009/11/01

PB - Elsevier

SP - 3725-3731

IS - 23

VL - 694

SN - 0022-328X

SN - 1872-8561

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2009_Parfenova,

author = {Lyudmila V. Parfenova and Vener Z Gabdrakhmanov and Leonard M. Khalilov and Usein M Dzhemilev},

title = {On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes},

journal = {Journal of Organometallic Chemistry},

year = {2009},

volume = {694},

publisher = {Elsevier},

month = {nov},

url = {https://doi.org/10.1016/j.jorganchem.2009.07.037},

number = {23},

pages = {3725--3731},

doi = {10.1016/j.jorganchem.2009.07.037}

}

MLA

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MLA Copy

Parfenova, Lyudmila V., et al. “On study of chemoselectivity of reaction of trialkylalanes with alkenes, catalyzed with Zr π-complexes.” Journal of Organometallic Chemistry, vol. 694, no. 23, Nov. 2009, pp. 3725-3731. https://doi.org/10.1016/j.jorganchem.2009.07.037.