Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides
Long Chen
1
,
Guangao Yu
1
,
Fang Li
1
,
Xiaolei Zhu
1
,
Bei Zhang
2
,
Rui Guo
2
,
Xiaozhi Li
1
,
Qihua Yang
2
,
Jin Shan
1
,
Chenchen Liu
1
,
Shenghua Liu
1
Publication type: Journal Article
Publication date: 2010-06-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
2-Phenylindenyl phosphine ligand can be changed into anionic phosphine ligand in situ and utilized in the palladium-catalyzed Buchwald/Hartwig amination reactions in DME, providing good to excellent yields of amination products from aryl chlorides, bromides and iodides. 31 P NMR studies show that the resonance for the anionic phosphine appeared between those of the (2-phenylindenyl)-dicyclohexyl phosphonium salt and (2-phenylindenyl)dicyclohexylphosphine. The calculated results were consistent with the experimental results.
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GOST
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Chen L. et al. Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 14. pp. 1768-1775.
GOST all authors (up to 50)
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Chen L., Yu G., Li F., Zhu X., Zhang B., Guo R., Li X., Yang Q., Shan J., Liu C., Liu S. Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides // Journal of Organometallic Chemistry. 2010. Vol. 695. No. 14. pp. 1768-1775.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2010.04.005
UR - https://doi.org/10.1016/j.jorganchem.2010.04.005
TI - Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides
T2 - Journal of Organometallic Chemistry
AU - Chen, Long
AU - Yu, Guangao
AU - Li, Fang
AU - Zhu, Xiaolei
AU - Zhang, Bei
AU - Guo, Rui
AU - Li, Xiaozhi
AU - Yang, Qihua
AU - Shan, Jin
AU - Liu, Chenchen
AU - Liu, Shenghua
PY - 2010
DA - 2010/06/01
PB - Elsevier
SP - 1768-1775
IS - 14
VL - 695
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
Copy
@article{2010_Chen,
author = {Long Chen and Guangao Yu and Fang Li and Xiaolei Zhu and Bei Zhang and Rui Guo and Xiaozhi Li and Qihua Yang and Jin Shan and Chenchen Liu and Shenghua Liu},
title = {Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides},
journal = {Journal of Organometallic Chemistry},
year = {2010},
volume = {695},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.jorganchem.2010.04.005},
number = {14},
pages = {1768--1775},
doi = {10.1016/j.jorganchem.2010.04.005}
}
Cite this
MLA
Copy
Chen, Long, et al. “Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides.” Journal of Organometallic Chemistry, vol. 695, no. 14, Jun. 2010, pp. 1768-1775. https://doi.org/10.1016/j.jorganchem.2010.04.005.