Synthesis, complexation behavior and application of a new diphosphite ligand in rhodium-catalyzed hydroformylation
Igor S Mikhel
1
,
Natalia V. Dubrovina
1
,
Ivan A Shuklov
1
,
Wolfgang Baumann
1
,
Detlef Selent
1
,
Haijun Jiao
1
,
Andrea Christiansen
2
,
Robert G. Franke
2
,
Armin Börner
1
1
2
Evonik Oxeno GmbH, Paul-Baumann-Str. 1, 45 772 Marl, Germany
|
Publication type: Journal Article
Publication date: 2011-09-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Oxidative coupling of 3-(3-tert-butyl-4-hydroxyphenyl)propionic acid methyl ester ( 2 ) gave dimethyl 3,3′-(5,5′-di-tert-butyl-6,6′-dihydroxybiphenyl-3,3′-diyl)-dipropionate ( 1c ), which upon phosphorylation/transesterification with a phosphochloridite derived from ( R )-binaphthol, formed the new unsymmetrical binaphthol-bridged diphosphite 4 . A rhodium catalyst based on 4 as ligand gave predominantly iso-selectivity in the hydroformylation of selected styrenes but opposite regioselectivity with 2,6-disubstituted derivatives. New chelate metal complexes (acac)RhL, PdCl 2 L and PtCl 2 L have been synthesized by reacting 4 with (acac)Rh(CO) 2 , PdCl 2 (MeCN) 2 and PtCl 2 (COD), respectively. The structure of obtained compounds is determined based on 1 H, 13 C, 31 P and 195 Pt NMR spectroscopy and mass spectrometry data.
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Total citations:
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Citations from 2024:
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GOST
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Mikhel I. S. et al. Synthesis, complexation behavior and application of a new diphosphite ligand in rhodium-catalyzed hydroformylation // Journal of Organometallic Chemistry. 2011. Vol. 696. No. 19. pp. 3050-3057.
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Mikhel I. S., Dubrovina N. V., Shuklov I. A., Baumann W., Selent D., Jiao H., Christiansen A., Franke R. G., Börner A. Synthesis, complexation behavior and application of a new diphosphite ligand in rhodium-catalyzed hydroformylation // Journal of Organometallic Chemistry. 2011. Vol. 696. No. 19. pp. 3050-3057.
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RIS
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TY - JOUR
DO - 10.1016/j.jorganchem.2011.05.004
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X11003172
TI - Synthesis, complexation behavior and application of a new diphosphite ligand in rhodium-catalyzed hydroformylation
T2 - Journal of Organometallic Chemistry
AU - Mikhel, Igor S
AU - Dubrovina, Natalia V.
AU - Shuklov, Ivan A
AU - Baumann, Wolfgang
AU - Selent, Detlef
AU - Jiao, Haijun
AU - Christiansen, Andrea
AU - Franke, Robert G.
AU - Börner, Armin
PY - 2011
DA - 2011/09/01
PB - Elsevier
SP - 3050-3057
IS - 19
VL - 696
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Mikhel,
author = {Igor S Mikhel and Natalia V. Dubrovina and Ivan A Shuklov and Wolfgang Baumann and Detlef Selent and Haijun Jiao and Andrea Christiansen and Robert G. Franke and Armin Börner},
title = {Synthesis, complexation behavior and application of a new diphosphite ligand in rhodium-catalyzed hydroformylation},
journal = {Journal of Organometallic Chemistry},
year = {2011},
volume = {696},
publisher = {Elsevier},
month = {sep},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X11003172},
number = {19},
pages = {3050--3057},
doi = {10.1016/j.jorganchem.2011.05.004}
}
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MLA
Copy
Mikhel, Igor S., et al. “Synthesis, complexation behavior and application of a new diphosphite ligand in rhodium-catalyzed hydroformylation.” Journal of Organometallic Chemistry, vol. 696, no. 19, Sep. 2011, pp. 3050-3057. https://linkinghub.elsevier.com/retrieve/pii/S0022328X11003172.
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