Mixed-valent ferrocenyltellurenyl halides. Synthesis, electrochemistry and unusual molecular structure
Yu. V. Torubaev
1
,
P. Mathur
2
,
Mohd Tauqeer
3
,
Suman Mukhopadhyay
2
,
A. A. Pasynskii
1
,
Alina Pavlova
1
,
2
Publication type: Journal Article
Publication date: 2014-01-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Halogenation of diferrocenyl ditelluride (Fc2Te2) allowed corresponding isostructural ferrocenyltellurenyls [FcTeX] (X= Cl (6), Br (7), X = I (8)). Their molecular structures in the solid state confirm them to be mixed-valent FcTe–TeX2Fc, however, the single band in 125Te NMR spectrum of 8 and electrochemical data suggests the monomeric [FcTeX] structure in the solution at room temperature. Remarkable bent of non-halogenated atom of Te towards the Fe atom observed in the solid state structures of 6–8, removes the Te atom from the plane of the related Cp ring (15°–20°) and may indicate the interaction of filled nonbonding 3d orbitals of Fe with the appropriate Te localized LUMO.
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Total citations:
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Citations from 2024:
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(9%)
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Torubaev Y. V. et al. Mixed-valent ferrocenyltellurenyl halides. Synthesis, electrochemistry and unusual molecular structure // Journal of Organometallic Chemistry. 2014. Vol. 749. pp. 115-119.
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Torubaev Y. V., Mathur P., Tauqeer M., Mukhopadhyay S., Kumar Lahiri G., Pasynskii A. A., Pavlova A., Grinberg V. A. Mixed-valent ferrocenyltellurenyl halides. Synthesis, electrochemistry and unusual molecular structure // Journal of Organometallic Chemistry. 2014. Vol. 749. pp. 115-119.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2013.09.017
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X13006852
TI - Mixed-valent ferrocenyltellurenyl halides. Synthesis, electrochemistry and unusual molecular structure
T2 - Journal of Organometallic Chemistry
AU - Torubaev, Yu. V.
AU - Mathur, P.
AU - Tauqeer, Mohd
AU - Mukhopadhyay, Suman
AU - Kumar Lahiri, Goutam
AU - Pasynskii, A. A.
AU - Pavlova, Alina
AU - Grinberg, V. A.
PY - 2014
DA - 2014/01/01
PB - Elsevier
SP - 115-119
VL - 749
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
Copy
@article{2014_Torubaev,
author = {Yu. V. Torubaev and P. Mathur and Mohd Tauqeer and Suman Mukhopadhyay and Goutam Kumar Lahiri and A. A. Pasynskii and Alina Pavlova and V. A. Grinberg},
title = {Mixed-valent ferrocenyltellurenyl halides. Synthesis, electrochemistry and unusual molecular structure},
journal = {Journal of Organometallic Chemistry},
year = {2014},
volume = {749},
publisher = {Elsevier},
month = {jan},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X13006852},
pages = {115--119},
doi = {10.1016/j.jorganchem.2013.09.017}
}
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