volume 789-790 pages 8-13

Triaryl/trialkylantimony(V) catecholates with electron-acceptor groups

Publication typeJournal Article
Publication date2015-08-01
scimago Q3
wos Q2
SJR0.385
CiteScore4.1
Impact factor2.4
ISSN0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A number of new antimony(V) complexes of type CatSbR3 (R = ethyl, o-tolyl, p-tolyl, p-fluorophenyl, p-chlorophenyl) with 4-chloro-3,6-di-tert-butyl-catecholato (4-Cl-3,6-DBCat), 6-chloro-, 6-bromo- and 6-nitro-3,5-di-tert-butyl-catecholato (6-X-3,5-DBCat, X = Cl, Br, NO2) redox-active ligands was synthesized and characterized. The molecular structures of (4-Cl-3,6-DBCat)Sb(o-Tol)3 (2), (6-Cl-3,5-DBCat)Sb(p-Tol)3 (7), (6-Br-3,5-DBCat)Sb(p-Tol)3 (8) in crystals were determined by single-crystal X-ray analysis. In the accordance with cyclic voltammetry data, the oxidation of complexes proceeds in two successive stages with a formation of mono- and dicationic derivatives. The modification of Ph groups at antimony with different substituents does not affect appreciably the redox potentials of complexes containing the electron-acceptor groups in redox-active ligand.
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Poddel'sky A. I. et al. Triaryl/trialkylantimony(V) catecholates with electron-acceptor groups // Journal of Organometallic Chemistry. 2015. Vol. 789-790. pp. 8-13.
GOST all authors (up to 50) Copy
Poddel'sky A. I., Smolyaninov I. V., Berberova N. T., Fukin G. K., Cherkasov V. K., Abakumov G. A. Triaryl/trialkylantimony(V) catecholates with electron-acceptor groups // Journal of Organometallic Chemistry. 2015. Vol. 789-790. pp. 8-13.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2015.04.045
UR - https://doi.org/10.1016/j.jorganchem.2015.04.045
TI - Triaryl/trialkylantimony(V) catecholates with electron-acceptor groups
T2 - Journal of Organometallic Chemistry
AU - Poddel'sky, Andrey I.
AU - Smolyaninov, Ivan V.
AU - Berberova, N. T.
AU - Fukin, Georgy K.
AU - Cherkasov, Vladimir Kuzmich
AU - Abakumov, G. A.
PY - 2015
DA - 2015/08/01
PB - Elsevier
SP - 8-13
VL - 789-790
SN - 0022-328X
SN - 1872-8561
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Poddel'sky,
author = {Andrey I. Poddel'sky and Ivan V. Smolyaninov and N. T. Berberova and Georgy K. Fukin and Vladimir Kuzmich Cherkasov and G. A. Abakumov},
title = {Triaryl/trialkylantimony(V) catecholates with electron-acceptor groups},
journal = {Journal of Organometallic Chemistry},
year = {2015},
volume = {789-790},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.jorganchem.2015.04.045},
pages = {8--13},
doi = {10.1016/j.jorganchem.2015.04.045}
}