Synthesis and structural characterization of lanthanum and cerium substituted cyclopentadienyl borohydride complexes
Publication type: Journal Article
Publication date: 2018-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The lanthanide borohydrides [Ln(BH4)3(THF)n] [Ln = La, n = 4 (1); Ln = Ce, n = 3.5] were treated with the substituted cyclopentadienyl potassium transfer agents KCptt (Cptt = C5H3tBu2-1,3), KCpttt (Cpttt = C5H2tBu3-1,2,4) and KCp′′′ (Cp′′′ = C5H2(SiMe3)3-1,2,4) in various reaction conditions to yield the heteroleptic lanthanide complexes [La(Cptt)2(μ-BH4)]2 (2), [La(Cpttt)(BH4)2(THF)2] (3), [La(Cpttt)(μ-BH4)2]6 (4), [Ce(Cpttt)(BH4)(μ-BH4)(THF)]2 (5), [La(Cpttt)2(BH4)] (6) and [Ln(Cp)2(BH4)(THF)] (Ln = La, 7; Ce, 8) by salt metathesis protocols. Complexes 1–8 have been variously characterized by single crystal X-ray diffraction, multi-nuclear NMR and FTIR spectroscopies, and elemental analyses.
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Total citations:
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Citations from 2025:
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Ortu F. et al. Synthesis and structural characterization of lanthanum and cerium substituted cyclopentadienyl borohydride complexes // Journal of Organometallic Chemistry. 2018. Vol. 857. pp. 45-51.
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Ortu F., Packer D., Liu J., Burton M., Formanuik A., Mills D. P. Synthesis and structural characterization of lanthanum and cerium substituted cyclopentadienyl borohydride complexes // Journal of Organometallic Chemistry. 2018. Vol. 857. pp. 45-51.
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RIS
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TY - JOUR
DO - 10.1016/j.jorganchem.2017.09.010
UR - https://doi.org/10.1016/j.jorganchem.2017.09.010
TI - Synthesis and structural characterization of lanthanum and cerium substituted cyclopentadienyl borohydride complexes
T2 - Journal of Organometallic Chemistry
AU - Ortu, Fabrizio
AU - Packer, Daniel
AU - Liu, Jingjing
AU - Burton, Matthew
AU - Formanuik, Alasdair
AU - Mills, David P.
PY - 2018
DA - 2018/02/01
PB - Elsevier
SP - 45-51
VL - 857
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{2018_Ortu,
author = {Fabrizio Ortu and Daniel Packer and Jingjing Liu and Matthew Burton and Alasdair Formanuik and David P. Mills},
title = {Synthesis and structural characterization of lanthanum and cerium substituted cyclopentadienyl borohydride complexes},
journal = {Journal of Organometallic Chemistry},
year = {2018},
volume = {857},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.jorganchem.2017.09.010},
pages = {45--51},
doi = {10.1016/j.jorganchem.2017.09.010}
}