Mechanochemical C–H bond activation: Synthesis of the tuckover hydrides, (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln(C5Me5) from solvent-free reactions of (C5Me5)2Ln(μ-Ph)2BPh2 with KC5Me5
Publication type: Journal Article
Publication date: 2019-10-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Attempts to synthesize the sterically crowded complexes (C5Me5)3Ln of the smallest lanthanide metals, Ln = Tm and Lu, from (C5Me5)2Ln(μ-Ph)2BPh2 and KC5Me5 via mechanochemical methods has revealed C–H bond activation chemistry: the tuckover hydride complexes, (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln(C5Me5), were observed in low crystalline yields. In the case of Ln = Yb, attempts to synthesize the cationic precursor, (C5Me5)2Yb(μ-Ph)2BPh2, from the reaction of (C5Me5)2Yb(η3-C3H5) and [HNEt3][BPh4] led to the reduction of the metal and the formation of the Yb(II) cationic complex, (C5Me5)Yb(μ-Ph)2BPh2.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
|
|
|
Chemistry
1 publication, 11.11%
|
|
|
Coordination Chemistry Reviews
1 publication, 11.11%
|
|
|
Green Chemistry
1 publication, 11.11%
|
|
|
Chemical Reviews
1 publication, 11.11%
|
|
|
Dalton Transactions
1 publication, 11.11%
|
|
|
Mendeleev Communications
1 publication, 11.11%
|
|
|
Journal of the American Chemical Society
1 publication, 11.11%
|
|
|
Organometallics
1 publication, 11.11%
|
|
|
1
|
Publishers
|
1
2
3
|
|
|
American Chemical Society (ACS)
3 publications, 33.33%
|
|
|
Elsevier
2 publications, 22.22%
|
|
|
Royal Society of Chemistry (RSC)
2 publications, 22.22%
|
|
|
MDPI
1 publication, 11.11%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 11.11%
|
|
|
1
2
3
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
9
Total citations:
9
Citations from 2025:
1
(11.11%)
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Woen D. H. et al. Mechanochemical C–H bond activation: Synthesis of the tuckover hydrides, (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln(C5Me5) from solvent-free reactions of (C5Me5)2Ln(μ-Ph)2BPh2 with KC5Me5 // Journal of Organometallic Chemistry. 2019. Vol. 899. p. 120885.
GOST all authors (up to 50)
Copy
Woen D. H., White J. R. K., Ziller J. W., EVANS W. J. Mechanochemical C–H bond activation: Synthesis of the tuckover hydrides, (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln(C5Me5) from solvent-free reactions of (C5Me5)2Ln(μ-Ph)2BPh2 with KC5Me5 // Journal of Organometallic Chemistry. 2019. Vol. 899. p. 120885.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2019.120885
UR - https://doi.org/10.1016/j.jorganchem.2019.120885
TI - Mechanochemical C–H bond activation: Synthesis of the tuckover hydrides, (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln(C5Me5) from solvent-free reactions of (C5Me5)2Ln(μ-Ph)2BPh2 with KC5Me5
T2 - Journal of Organometallic Chemistry
AU - Woen, David H
AU - White, Jessica R K
AU - Ziller, Joseph W.
AU - EVANS, WILLIAM J.
PY - 2019
DA - 2019/10/01
PB - Elsevier
SP - 120885
VL - 899
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Woen,
author = {David H Woen and Jessica R K White and Joseph W. Ziller and WILLIAM J. EVANS},
title = {Mechanochemical C–H bond activation: Synthesis of the tuckover hydrides, (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln(C5Me5) from solvent-free reactions of (C5Me5)2Ln(μ-Ph)2BPh2 with KC5Me5},
journal = {Journal of Organometallic Chemistry},
year = {2019},
volume = {899},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.jorganchem.2019.120885},
pages = {120885},
doi = {10.1016/j.jorganchem.2019.120885}
}