Undecenoic acid-based polydimethylsiloxanes obtained by hydrosilylation and hydrothiolation reactions
Sergey A Milenin
1
,
Fedor V Drozdov
1
,
Elizaveta V Selezneva
1
,
M. I. Buzin
3, 4, 5
,
Aziz M. Muzafarov
1, 6
4
RUSSIAN ACADEMY OF SCIENCES
5
28 Vavilov st. Moscow 119991 Russia
|
Publication type: Journal Article
Publication date: 2020-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
In the present work for the first time polydimethylsiloxanes containing a rigid segment based on N,N-(ethane-1,2-diyl)diundec-10-enamide in the main chain were synthesized by hydrosilylation and hydrothiolation reactions. As a result, oligomers and polymers with various molecular weights from 3000 to 52000 (g mol−1, GPC) were obtained. The thermal properties of the obtained copolymers were investigated by TGA and DSC analysis. All PDMS copolymers containing different amounts of diamide fragments exhibit properties that are distinct from pure polydimethylsiloxane, which indicates a significant influence of a rigid fragment capable of forming hydrogen bonds on the phase behavior of the resulting copolymers.
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Total citations:
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Citations from 2025:
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GOST
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Milenin S. A. et al. Undecenoic acid-based polydimethylsiloxanes obtained by hydrosilylation and hydrothiolation reactions // Journal of Organometallic Chemistry. 2020. Vol. 907. p. 121074.
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Milenin S. A., Drozdov F. V., Selezneva E. V., Ardabevskaia S. N., Buzin M. I., Muzafarov A. M. Undecenoic acid-based polydimethylsiloxanes obtained by hydrosilylation and hydrothiolation reactions // Journal of Organometallic Chemistry. 2020. Vol. 907. p. 121074.
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RIS
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TY - JOUR
DO - 10.1016/j.jorganchem.2019.121074
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X19305170
TI - Undecenoic acid-based polydimethylsiloxanes obtained by hydrosilylation and hydrothiolation reactions
T2 - Journal of Organometallic Chemistry
AU - Milenin, Sergey A
AU - Drozdov, Fedor V
AU - Selezneva, Elizaveta V
AU - Ardabevskaia, Sofia N
AU - Buzin, M. I.
AU - Muzafarov, Aziz M.
PY - 2020
DA - 2020/02/01
PB - Elsevier
SP - 121074
VL - 907
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2020_Milenin,
author = {Sergey A Milenin and Fedor V Drozdov and Elizaveta V Selezneva and Sofia N Ardabevskaia and M. I. Buzin and Aziz M. Muzafarov},
title = {Undecenoic acid-based polydimethylsiloxanes obtained by hydrosilylation and hydrothiolation reactions},
journal = {Journal of Organometallic Chemistry},
year = {2020},
volume = {907},
publisher = {Elsevier},
month = {feb},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X19305170},
pages = {121074},
doi = {10.1016/j.jorganchem.2019.121074}
}