Synthesis, crystal structure and electrochemical properties of poly(cadmium 1,1′-ferrocenediyl-bis(H-phosphinate))
Publication type: Journal Article
Publication date: 2020-05-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The new redox active coordination polymer [Cd(H2O)2(fc(PHOO)2)·2H2O]n (fc = 1,1′-ferrocenediyl) was synthesized and structurally characterized by single-crystal X-ray diffraction. In this compound cadmium atoms are bound by phosphinate fragments to give infinite chains, the latter are interconnected by ferrocene groups to form 2D coordination polymer. Electrochemical properties of CP were investigated. It’s found that Cd-polymer is harder to oxidize than its isostructural cobalt analogue. This means that increase in the length of the M − O bond in coordination polymer, oxidation becomes harder.
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Total citations:
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Citations from 2024:
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Shekurov R. et al. Synthesis, crystal structure and electrochemical properties of poly(cadmium 1,1′-ferrocenediyl-bis(H-phosphinate)) // Journal of Organometallic Chemistry. 2020. Vol. 914. p. 121233.
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Shekurov R. P., Khrizanforov M., R. Islamov D., Gerasimova T. I., Zagidullin A. A., Budnikova Y. H., Miluykov V. Synthesis, crystal structure and electrochemical properties of poly(cadmium 1,1′-ferrocenediyl-bis(H-phosphinate)) // Journal of Organometallic Chemistry. 2020. Vol. 914. p. 121233.
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TY - JOUR
DO - 10.1016/j.jorganchem.2020.121233
UR - https://doi.org/10.1016/j.jorganchem.2020.121233
TI - Synthesis, crystal structure and electrochemical properties of poly(cadmium 1,1′-ferrocenediyl-bis(H-phosphinate))
T2 - Journal of Organometallic Chemistry
AU - Shekurov, Ruslan P
AU - Khrizanforov, Mikhail
AU - R. Islamov, Daut
AU - Gerasimova, Tatiana I.
AU - Zagidullin, Almaz A
AU - Budnikova, Yulia H.
AU - Miluykov, Vasili
PY - 2020
DA - 2020/05/01
PB - Elsevier
SP - 121233
VL - 914
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2020_Shekurov,
author = {Ruslan P Shekurov and Mikhail Khrizanforov and Daut R. Islamov and Tatiana I. Gerasimova and Almaz A Zagidullin and Yulia H. Budnikova and Vasili Miluykov},
title = {Synthesis, crystal structure and electrochemical properties of poly(cadmium 1,1′-ferrocenediyl-bis(H-phosphinate))},
journal = {Journal of Organometallic Chemistry},
year = {2020},
volume = {914},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.jorganchem.2020.121233},
pages = {121233},
doi = {10.1016/j.jorganchem.2020.121233}
}