PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode
1
Plug Power Inc., 968 Albany-Shaker Road, Latham, NY 12110, USA
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Publication type: Journal Article
Publication date: 2006-08-01
scimago Q1
wos Q1
SJR: 1.784
CiteScore: 14.9
Impact factor: 7.9
ISSN: 03787753, 18732755
Physical and Theoretical Chemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
The impacts of unprotected start up and shut down on fuel cell performance degradation was investigated using both single cell and dual cell configurations. It was found that the air/fuel boundary developed at the anode side after a fuel cell shut down or during its restart caused extremely quick degradation of the cathode. The thickness, the electrochemical active surface area, and the performance of the cathode catalyst layer were significantly reduced. By using a dual cell configuration, cathode potential as high as two times of open circuit voltage was measured, and the corrosion current flowing externally between the two cells was detected and quantified. Carbon catalyst-support corrosion/oxidation at such a high potential was largely responsible for the accelerated fuel cell performance degradation.
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434
Total citations:
434
Citations from 2024:
49
(11.29%)
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GOST
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Tang H. et al. PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode // Journal of Power Sources. 2006. Vol. 158. No. 2. pp. 1306-1312.
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Tang H., Qi Z., Ramani M., Elter J. F. PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode // Journal of Power Sources. 2006. Vol. 158. No. 2. pp. 1306-1312.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.jpowsour.2005.10.059
UR - https://doi.org/10.1016/j.jpowsour.2005.10.059
TI - PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode
T2 - Journal of Power Sources
AU - Tang, Hao
AU - Qi, Zhigang
AU - Ramani, Manikandan
AU - Elter, John F.
PY - 2006
DA - 2006/08/01
PB - Elsevier
SP - 1306-1312
IS - 2
VL - 158
SN - 0378-7753
SN - 1873-2755
ER -
Cite this
BibTex (up to 50 authors)
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@article{2006_Tang,
author = {Hao Tang and Zhigang Qi and Manikandan Ramani and John F. Elter},
title = {PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode},
journal = {Journal of Power Sources},
year = {2006},
volume = {158},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.jpowsour.2005.10.059},
number = {2},
pages = {1306--1312},
doi = {10.1016/j.jpowsour.2005.10.059}
}
Cite this
MLA
Copy
Tang, Hao, et al. “PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode.” Journal of Power Sources, vol. 158, no. 2, Aug. 2006, pp. 1306-1312. https://doi.org/10.1016/j.jpowsour.2005.10.059.