volume 198 pages 496-505

PH control of the structure, composition, and catalytic activity of sulfated zirconia

V. V. Ivanov 1, 2
Lyudmila L Yurkova 5
Nadezhda N Gubanova 1, 4
Anatoly S Lermontov 1
Larisa P Vasilyeva 6
Sharp Melissa 7
P. Klaus Pranzas 7
Yuri D. Tretyakov 2
Publication typeJournal Article
Publication date2013-02-01
scimago Q2
wos Q1
SJR0.629
CiteScore6.8
Impact factor3.5
ISSN00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
We report a detailed study of structural and chemical transformations of amorphous hydrous zirconia into sulfated zirconia-based superacid catalysts. Precipitation pH is shown to be the key factor governing structure, composition and properties of amorphous sulfated zirconia gels and nanocrystalline sulfated zirconia. Increase in precipitation pH leads to substantial increase of surface fractal dimension (up to � 2.7) of amorphous sulfated zirconia gels, and consequently to increase in specific surface area (up to � 80 m 2 /g) and simultaneously to decrease in sulfate content and total acidity of
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GOST Copy
Ivanov V. V. et al. PH control of the structure, composition, and catalytic activity of sulfated zirconia // Journal of Solid State Chemistry. 2013. Vol. 198. pp. 496-505.
GOST all authors (up to 50) Copy
Ivanov V. V., Baranchikov A. E., Kopitsa G. P., Lermontov S. A., Yurkova L. L., Gubanova N. N., Ivanova O., Lermontov A. S., Rumyantseva M., Vasilyeva L. P., Melissa S., Pranzas P. K., Tretyakov Y. D. PH control of the structure, composition, and catalytic activity of sulfated zirconia // Journal of Solid State Chemistry. 2013. Vol. 198. pp. 496-505.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jssc.2012.11.022
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022459612007062
TI - PH control of the structure, composition, and catalytic activity of sulfated zirconia
T2 - Journal of Solid State Chemistry
AU - Ivanov, V. V.
AU - Baranchikov, Alexander E
AU - Kopitsa, G. P.
AU - Lermontov, Sergey A
AU - Yurkova, Lyudmila L
AU - Gubanova, Nadezhda N
AU - Ivanova, Oxana
AU - Lermontov, Anatoly S
AU - Rumyantseva, M.
AU - Vasilyeva, Larisa P
AU - Melissa, Sharp
AU - Pranzas, P. Klaus
AU - Tretyakov, Yuri D.
PY - 2013
DA - 2013/02/01
PB - Elsevier
SP - 496-505
VL - 198
SN - 0022-4596
SN - 1095-726X
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Ivanov,
author = {V. V. Ivanov and Alexander E Baranchikov and G. P. Kopitsa and Sergey A Lermontov and Lyudmila L Yurkova and Nadezhda N Gubanova and Oxana Ivanova and Anatoly S Lermontov and M. Rumyantseva and Larisa P Vasilyeva and Sharp Melissa and P. Klaus Pranzas and Yuri D. Tretyakov},
title = {PH control of the structure, composition, and catalytic activity of sulfated zirconia},
journal = {Journal of Solid State Chemistry},
year = {2013},
volume = {198},
publisher = {Elsevier},
month = {feb},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022459612007062},
pages = {496--505},
doi = {10.1016/j.jssc.2012.11.022}
}