Molecular Catalysis, volume 484, pages 110727
CuCl-based SILCs in the thiophene oxidation – Experimental and DFT-assisted study
Ivanin I A
1
,
Zubanova E M
1
,
Tarkhanova I G
,
Buryak A.K
2
,
Ali Zade A G
1
,
Zelikman V M
1
,
Golubeva Elena N
1
,
Tarkhanova I G
1
Publication type: Journal Article
Publication date: 2020-03-01
Catalysis
Physical and Theoretical Chemistry
Process Chemistry and Technology
Abstract
Supported ionic liquid catalysts (SILC) on Silochrome for thiophene peroxide oxidation were synthesized. They consisted of imidazolium and alkylammonium with Cu(I) and Fe(III) chloro-anions. The composition and structure of the catalysts were investigated by physicochemical methods. Quantum chemical calculations of the geometric structure and the formation energy of π-complexes of thiophene with anionic copper (I) chlorocomplexes were carried out. Based on quantum chemical calculations and experimental data with radical scavengers, the catalytic reaction mechanism has been proposed. It involves the participation of superoxide ions and copper hydroxochloride complexes. The contribution of hydroxyl radicals to thiophene oxidation probably depends on the nuclearity of copper complexes in the catalyst.
Citations by journals
|
1
|
|
|
Doklady Chemistry
|
Doklady Chemistry
1 publication, 25%
|
|
Kataliz v promyshlennosti
|
Kataliz v promyshlennosti, 1, 25%
Kataliz v promyshlennosti
1 publication, 25%
|
|
Kinetics and Catalysis
|
Kinetics and Catalysis
1 publication, 25%
|
|
Catalysis in Industry
|
Catalysis in Industry
1 publication, 25%
|
|
1
|
Citations by publishers
|
1
2
3
|
|
|
Pleiades Publishing
|
Pleiades Publishing
3 publications, 75%
|
|
Kalvis
|
Kalvis, 1, 25%
Kalvis
1 publication, 25%
|
|
1
2
3
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023],"ids":[0,0],"codes":[0,0],"imageUrls":["",""],"datasets":[{"label":"Citations number","data":[1,3],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":["25","75"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Doklady Chemistry","Kataliz v promyshlennosti","Kinetics and Catalysis","Catalysis in Industry"],"ids":[11308,25503,19841,4253],"codes":[0,0,0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp"],"datasets":[{"label":"","data":[1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[25,25,25,25],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Pleiades Publishing","Kalvis"],"ids":[101,6927],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp",""],"datasets":[{"label":"","data":[3,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[75,25],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Ivanin I. A. et al. CuCl-based SILCs in the thiophene oxidation – Experimental and DFT-assisted study // Molecular Catalysis. 2020. Vol. 484. p. 110727.
GOST all authors (up to 50)
Copy
Ivanin I. A., Ali Zade A. G., Golubeva E. N., Zubanova E. M., Zelikman V. M., Buryak A., Tarkhanova I. G., Golubeva E. N., Tarkhanova I. G. CuCl-based SILCs in the thiophene oxidation – Experimental and DFT-assisted study // Molecular Catalysis. 2020. Vol. 484. p. 110727.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.mcat.2019.110727
UR - https://doi.org/10.1016%2Fj.mcat.2019.110727
TI - CuCl-based SILCs in the thiophene oxidation – Experimental and DFT-assisted study
T2 - Molecular Catalysis
AU - Ivanin, I A
AU - Ali Zade, A G
AU - Golubeva, E. N.
AU - Zubanova, E M
AU - Zelikman, V M
AU - Buryak, A.K
AU - Tarkhanova, I G
AU - Golubeva, Elena N
AU - Tarkhanova, I G
PY - 2020
DA - 2020/03/01 00:00:00
PB - Elsevier
SP - 110727
VL - 484
SN - 2468-8231
ER -
Cite this
BibTex
Copy
@article{2020_Ivanin,
author = {I A Ivanin and A G Ali Zade and E. N. Golubeva and E M Zubanova and V M Zelikman and A.K Buryak and I G Tarkhanova and Elena N Golubeva and I G Tarkhanova},
title = {CuCl-based SILCs in the thiophene oxidation – Experimental and DFT-assisted study},
journal = {Molecular Catalysis},
year = {2020},
volume = {484},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016%2Fj.mcat.2019.110727},
pages = {110727},
doi = {10.1016/j.mcat.2019.110727}
}
Profiles