Mendeleev Communications

, том 22 , издание 1 , страницы 32-34

Metathesis of azomethine imines in the reaction of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with carbonyl compounds

Тип публикации: Journal Article

Дата публикации: 2012-01-31

OOO Zhurnal "Mendeleevskie Soobshcheniya"

Mendeleev Communications

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SJR: 0.305

CiteScore: 3

Impact factor: 1.7

ISSN: 09599436, 1364551X

DOI: 10.1016/j.mencom.2012.01.012

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General Chemistry

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An interaction of carbonyl compounds (isatins, 4-nitrobenzaldehyde) with azomethine imines generated by the diaziridine ring opening in 6-aryl-1,5-diazabicyclo[3.1.0]hexanes in the presence of BF 3 ·Et 2 O as a catalyst induced the metathesis to other azomethine imines with the elimination of aldehydes ArCHO. New azomethine imines were trapped with diethyl acetylenedicarboxylate, otherwise they transformed to the corresponding pyrazolines due to a 1,4-H shift.

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Petukhova V. Y. et al. Metathesis of azomethine imines in the reaction of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with carbonyl compounds // Mendeleev Communications. 2012. Vol. 22. No. 1. pp. 32-34.

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Petukhova V. Y., Pleshchev M. I., Fershtat L. L., Kuznetsov V. V., Kachala V. V., Makhova N. N. Metathesis of azomethine imines in the reaction of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with carbonyl compounds // Mendeleev Communications. 2012. Vol. 22. No. 1. pp. 32-34.

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TY - JOUR

DO - 10.1016/j.mencom.2012.01.012

UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943612000132

TI - Metathesis of azomethine imines in the reaction of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with carbonyl compounds

T2 - Mendeleev Communications

AU - Petukhova, Vera Yu.

AU - Pleshchev, Mikhail I

AU - Fershtat, Leonid L.

AU - Kuznetsov, V. V.

AU - Kachala, Vadim V.

AU - Makhova, Nina N.

PY - 2012

DA - 2012/01/31

PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"

SP - 32-34

IS - 1

VL - 22

SN - 0959-9436

SN - 1364-551X

ER -

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@article{2012_Petukhova,

author = {Vera Yu. Petukhova and Mikhail I Pleshchev and Leonid L. Fershtat and V. V. Kuznetsov and Vadim V. Kachala and Nina N. Makhova},

title = {Metathesis of azomethine imines in the reaction of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with carbonyl compounds},

journal = {Mendeleev Communications},

year = {2012},

volume = {22},

publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},

month = {jan},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943612000132},

number = {1},

pages = {32--34},

doi = {10.1016/j.mencom.2012.01.012}

}

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Petukhova, Vera Yu., et al. “Metathesis of azomethine imines in the reaction of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with carbonyl compounds.” Mendeleev Communications, vol. 22, no. 1, Jan. 2012, pp. 32-34. https://linkinghub.elsevier.com/retrieve/pii/S0959943612000132.