Mendeleev Communications
,  volume 25 ,  issue 2 ,  pages 135-137

New cascade transformations of 3-(2-aminophenyl- amino)-5,5-dimethyl-2-cyclohexen-1-one

Publication type: Journal Article
Publication date: 2015-03-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The reaction of 3-(2-aminophenylamino)-5,5-dimethyl-2-cyclohexen-1-one with alloxan results in 3,3-dimethyl-1,2,3,4,10,11-hexa- hydrospiro(1H-dibenzo[b,e][1,4]diazepine)-11,5’-pyrimidine-1,2’,4’,6’-tetraone or N-aminocarbonyl-1-(2-aminophenyl)-3-hydroxy- 6,6-dimethyl-2,4-dioxo-2,3,4,5,6,7-hexahydro-1H-indole-3-carboxamide. The latter undergoes isomerization on dissolution in DMSO or DMF to give 5-[2-(2-aminophenylamino)-4,4-dimethyl-6-oxocyclohexenyl]-5-hydroxypyrimidine-2,4,6(1H,3H,6H)-trione, thus demonstrating a new example of ring–ring tautomerism.
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Ukhin L. Yu. et al. New cascade transformations of 3-(2-aminophenyl- amino)-5,5-dimethyl-2-cyclohexen-1-one // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 135-137.
GOST all authors (up to 50) Copy
Ukhin L. Yu., Suponitsky K. Y., Shepelenko E. N., Belousova L. V., Popova O. S., Borodkin G. S. New cascade transformations of 3-(2-aminophenyl- amino)-5,5-dimethyl-2-cyclohexen-1-one // Mendeleev Communications. 2015. Vol. 25. No. 2. pp. 135-137.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2015.03.020
UR - https://doi.org/10.1016/j.mencom.2015.03.020
TI - New cascade transformations of 3-(2-aminophenyl- amino)-5,5-dimethyl-2-cyclohexen-1-one
T2 - Mendeleev Communications
AU - Ukhin, Lev Yu
AU - Suponitsky, Kyrill Yu.
AU - Shepelenko, Eugenii N
AU - Belousova, Lyudmila V
AU - Popova, Oxana S
AU - Borodkin, Gennadii S
PY - 2015
DA - 2015/03/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 135-137
IS - 2
VL - 25
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Ukhin,
author = {Lev Yu Ukhin and Kyrill Yu. Suponitsky and Eugenii N Shepelenko and Lyudmila V Belousova and Oxana S Popova and Gennadii S Borodkin},
title = {New cascade transformations of 3-(2-aminophenyl- amino)-5,5-dimethyl-2-cyclohexen-1-one},
journal = {Mendeleev Communications},
year = {2015},
volume = {25},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://doi.org/10.1016/j.mencom.2015.03.020},
number = {2},
pages = {135--137},
doi = {10.1016/j.mencom.2015.03.020}
}
MLA
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MLA Copy
Ukhin, Lev Yu., et al. “New cascade transformations of 3-(2-aminophenyl- amino)-5,5-dimethyl-2-cyclohexen-1-one.” Mendeleev Communications, vol. 25, no. 2, Mar. 2015, pp. 135-137. https://doi.org/10.1016/j.mencom.2015.03.020.