Mendeleev Communications

, volume 25 , issue 6 , pages 415-416

Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers

Konstantin S Rodygin ¹

Anton A Kostin ¹

Valentine P. Ananikov ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

St. Petersburg State University, 119034 St. Petersburg, Russian Federation |

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation |

Publication type: Journal Article

Publication date: 2015-11-01

OOO Zhurnal "Mendeleevskie Soobshcheniya"

Mendeleev Communications

scimago Q3

wos Q3

SJR: 0.305

CiteScore: 3.0

Impact factor: 1.7

ISSN: 09599436, 1364551X

DOI: 10.1016/j.mencom.2015.11.004

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General Chemistry

Abstract

Calcium carbide was studied as a useful solid-state reagent to incorporate acetylene unit into synthetic procedures. Atom-economic thiol-yne click reaction was successfully performed with single and double additions. Heterocyclic thiols and aliphatic dithiols reacted with acetylene generated in situ from calcium carbide to afford corresponding vinyl sulfides and bis(thiovinyl)ethers in good to high yields.

Found

1 citation

Vereshchagin Anatoly

DSc in Chemistry

162 publications, 2 697 citations, 8 reviews

h-index: 28

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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Rodygin K. S. et al. Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers // Mendeleev Communications. 2015. Vol. 25. No. 6. pp. 415-416.

GOST all authors (up to 50) Copy

Rodygin K. S., Kostin A. A., Ananikov V. P. Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers // Mendeleev Communications. 2015. Vol. 25. No. 6. pp. 415-416.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.mencom.2015.11.004

UR - https://doi.org/10.1016/j.mencom.2015.11.004

TI - Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers

T2 - Mendeleev Communications

AU - Rodygin, Konstantin S

AU - Kostin, Anton A

AU - Ananikov, Valentine P.

PY - 2015

DA - 2015/11/01

PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"

SP - 415-416

IS - 6

VL - 25

SN - 0959-9436

SN - 1364-551X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2015_Rodygin,

author = {Konstantin S Rodygin and Anton A Kostin and Valentine P. Ananikov},

title = {Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers},

journal = {Mendeleev Communications},

year = {2015},

volume = {25},

publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},

month = {nov},

url = {https://doi.org/10.1016/j.mencom.2015.11.004},

number = {6},

pages = {415--416},

doi = {10.1016/j.mencom.2015.11.004}

}

MLA

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Rodygin, Konstantin S., et al. “Calcium carbide as a convenient acetylene source in the synthesis of unsaturated sulfides, promising functionalized monomers.” Mendeleev Communications, vol. 25, no. 6, Nov. 2015, pp. 415-416. https://doi.org/10.1016/j.mencom.2015.11.004.