Highly enantioselective amination of η3-(2-fluorocycloheptenyl)palladium complexes bearing chiral P,P- and P,N-ligands
Angelina Yu Bobrova
1
,
Maxim I. Novikov
1
,
Roman G. Novikov
1
,
Alexander A. Korlyukov
3
,
Yury V Tomilov
1
Publication type: Journal Article
Publication date: 2022-09-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The key enantioselectivity-determining step in Pd-catalyzed asymmetric amination of 2-fluoroallylic substrates was optimized using model reaction of η 3 -(2-fluorocycloheptenyl)-palladium complexes bearing chiral P,P- and P,N-ligands with various amines. ( S )-ButPHOX was found to be the most effective ligand allowing the formation of 2-fluoroallyl amines and anilines with high enantioselectivity.
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Total citations:
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Citations from 2025:
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GOST
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Yu Bobrova A. et al. Highly enantioselective amination of η3-(2-fluorocycloheptenyl)palladium complexes bearing chiral P,P- and P,N-ligands // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 619-621.
GOST all authors (up to 50)
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Yu Bobrova A., Novikov M. I., Novikov R. G., Dorovatovskii P. V., Volodin A. D., Korlyukov A. A., Tomilov Y. V. Highly enantioselective amination of η3-(2-fluorocycloheptenyl)palladium complexes bearing chiral P,P- and P,N-ligands // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 619-621.
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RIS
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.016
UR - https://doi.org/10.1016/j.mencom.2022.09.016
TI - Highly enantioselective amination of η3-(2-fluorocycloheptenyl)palladium complexes bearing chiral P,P- and P,N-ligands
T2 - Mendeleev Communications
AU - Yu Bobrova, Angelina
AU - Novikov, Maxim I.
AU - Novikov, Roman G.
AU - Dorovatovskii, Pavel V.
AU - Volodin, Alexander D
AU - Korlyukov, Alexander A.
AU - Tomilov, Yury V
PY - 2022
DA - 2022/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 619-621
IS - 5
VL - 32
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2022_Yu Bobrova,
author = {Angelina Yu Bobrova and Maxim I. Novikov and Roman G. Novikov and Pavel V. Dorovatovskii and Alexander D Volodin and Alexander A. Korlyukov and Yury V Tomilov},
title = {Highly enantioselective amination of η3-(2-fluorocycloheptenyl)palladium complexes bearing chiral P,P- and P,N-ligands},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://doi.org/10.1016/j.mencom.2022.09.016},
number = {5},
pages = {619--621},
doi = {10.1016/j.mencom.2022.09.016}
}
Cite this
MLA
Copy
Yu. Bobrova, Angelina, et al. “Highly enantioselective amination of η3-(2-fluorocycloheptenyl)palladium complexes bearing chiral P,P- and P,N-ligands.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 619-621. https://doi.org/10.1016/j.mencom.2022.09.016.