Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]
Ilya Yakushev
1
,
Nadezhda K Ogarkova
1, 2
,
Evgeny V. Khramov
1, 3
,
Nadezhda S Smirnova
1, 4
,
Maria Yu. Nesterenko
1
,
Maria V Panina
1
,
Anna S. POPOVA
1, 2
Publication type: Journal Article
Publication date: 2023-07-17
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Novel square-planar Pt-based heterometallic complexes with ferrocenecarboxylic acid were prepared in two steps from (tetrapyridine)platinum diacetate [PtPy4](OAc)2. The crystal structure of [PtPy4](FcCOO)2 and [PtPy2(FcCOO)2] was established by single crystal X-ray diffraction. Subsequent thermal transformation of a trinuclear compound [PtPy2(FcCOO)2] to a bimetallic Pt–Fe phase was studied by XAFS techniques.
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Yakushev I. et al. Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2] // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 487-490.
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Yakushev I., Ogarkova N. K., Khramov E. V., Smirnova N. S., Yu. Nesterenko M., Cherkashina N. V., Medvedev A. G., Panina M. V., Vargaftik M. N., POPOVA A. S. Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2] // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 487-490.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.015
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943623001864
TI - Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]
T2 - Mendeleev Communications
AU - Yakushev, Ilya
AU - Ogarkova, Nadezhda K
AU - Khramov, Evgeny V.
AU - Smirnova, Nadezhda S
AU - Yu. Nesterenko, Maria
AU - Cherkashina, Natalia V
AU - Medvedev, Alexander G.
AU - Panina, Maria V
AU - Vargaftik, Michael N
AU - POPOVA, Anna S.
PY - 2023
DA - 2023/07/17
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 487-490
IS - 4
VL - 33
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2023_Yakushev,
author = {Ilya Yakushev and Nadezhda K Ogarkova and Evgeny V. Khramov and Nadezhda S Smirnova and Maria Yu. Nesterenko and Natalia V Cherkashina and Alexander G. Medvedev and Maria V Panina and Michael N Vargaftik and Anna S. POPOVA},
title = {Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943623001864},
number = {4},
pages = {487--490},
doi = {10.1016/j.mencom.2023.06.015}
}
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MLA
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Yakushev, Ilya, et al. “Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2].” Mendeleev Communications, vol. 33, no. 4, Jul. 2023, pp. 487-490. https://linkinghub.elsevier.com/retrieve/pii/S0959943623001864.