Isomeric indolizine-based π-expanded push–pull NLO-chromophores: Synthesis and comparative study
Alexey A Kalinin
1
,
Gulshat G. Yusupova
1
,
Yulia B. Dudkina
1
,
Liliya N. Islamova
1
,
Alina I Levitskaya
1
,
Timur I Burganov
1
,
Publication type: Journal Article
Publication date: 2018-03-01
scimago Q2
wos Q2
SJR: 0.628
CiteScore: 8.0
Impact factor: 4.7
ISSN: 00222860, 18728014
Organic Chemistry
Inorganic Chemistry
Spectroscopy
Analytical Chemistry
Abstract
Two series of isomeric indolizine-based chromophores with isophorone rings as a π-bridge have been synthesized and systematically investigated. The chromophores have a high thermal stability: the decomposition temperature is above 238 °C. For isomers with 1-methyl-2-phenylindolizin-3-yl (MPI-3) donor group higher values of β are predicted in comparison with those having 3-methyl-2-phenylindolizin-1-yl (MPI-1) donor group. This is in good agreement with the experimental and theoretical values of the HOMO-LUMO energy gap. Indolizine-based chromophores with barbituric acceptor and isophorone moieties in the π-bridge demonstrate the combination of good characteristics.
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Total citations:
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GOST
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Kalinin A. A. et al. Isomeric indolizine-based π-expanded push–pull NLO-chromophores: Synthesis and comparative study // Journal of Molecular Structure. 2018. Vol. 1156. pp. 74-82.
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Kalinin A. A., Yusupova G. G., Dudkina Y. B., Islamova L. N., Levitskaya A. I., Balakina M. Y., Burganov T. I., Khamatgalimov A., Katsyuba S. A., Budnikova Y. H. Isomeric indolizine-based π-expanded push–pull NLO-chromophores: Synthesis and comparative study // Journal of Molecular Structure. 2018. Vol. 1156. pp. 74-82.
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RIS
Copy
TY - JOUR
DO - 10.1016/j.molstruc.2017.11.077
UR - https://doi.org/10.1016/j.molstruc.2017.11.077
TI - Isomeric indolizine-based π-expanded push–pull NLO-chromophores: Synthesis and comparative study
T2 - Journal of Molecular Structure
AU - Kalinin, Alexey A
AU - Yusupova, Gulshat G.
AU - Dudkina, Yulia B.
AU - Islamova, Liliya N.
AU - Levitskaya, Alina I
AU - Balakina, Marina Yu.
AU - Burganov, Timur I
AU - Khamatgalimov, A.R
AU - Katsyuba, Sergey A.
AU - Budnikova, Yulia H.
PY - 2018
DA - 2018/03/01
PB - Elsevier
SP - 74-82
VL - 1156
SN - 0022-2860
SN - 1872-8014
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Kalinin,
author = {Alexey A Kalinin and Gulshat G. Yusupova and Yulia B. Dudkina and Liliya N. Islamova and Alina I Levitskaya and Marina Yu. Balakina and Timur I Burganov and A.R Khamatgalimov and Sergey A. Katsyuba and Yulia H. Budnikova},
title = {Isomeric indolizine-based π-expanded push–pull NLO-chromophores: Synthesis and comparative study},
journal = {Journal of Molecular Structure},
year = {2018},
volume = {1156},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.molstruc.2017.11.077},
pages = {74--82},
doi = {10.1016/j.molstruc.2017.11.077}
}