Synthesis, structure and peculiarity of conformational behavior of 1,5-diazabicyclo[3.1.0]hexanes
Publication type: Journal Article
Publication date: 2022-12-01
scimago Q2
wos Q2
SJR: 0.628
CiteScore: 8.0
Impact factor: 4.7
ISSN: 00222860, 18728014
Organic Chemistry
Inorganic Chemistry
Spectroscopy
Analytical Chemistry
Abstract
• The anomeric effect is not always decisive for “boat” conformation stabilization • Intermolecular interactions change the conformational structure of diazabicyclohexane • The close packing principle is observed in modeling the crystal packing For the first time, a number of new 3,3-dimethyl-1,5-diazabicyclo[3.1.0]hexanes has been obtained and characterized by X-ray diffraction analysis, spectral and physicochemical methods. The features of the enantiomers of the considered compounds are analysed by quantum chemistry methods and crystal packing modeling methods. It is shown that intermolecular interactions in solid state radically change the nature of the conformational structure of 1,5-diazabicyclo[3.1.0]hexanes.
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Total citations:
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Citations from 2025:
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Kuznetsov V. V. et al. Synthesis, structure and peculiarity of conformational behavior of 1,5-diazabicyclo[3.1.0]hexanes // Journal of Molecular Structure. 2022. Vol. 1269. p. 133856.
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Kuznetsov V. V., Khakimov D., Dmitrenok A. S., Goloveshkin A. S. Synthesis, structure and peculiarity of conformational behavior of 1,5-diazabicyclo[3.1.0]hexanes // Journal of Molecular Structure. 2022. Vol. 1269. p. 133856.
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TY - JOUR
DO - 10.1016/j.molstruc.2022.133856
UR - https://doi.org/10.1016/j.molstruc.2022.133856
TI - Synthesis, structure and peculiarity of conformational behavior of 1,5-diazabicyclo[3.1.0]hexanes
T2 - Journal of Molecular Structure
AU - Kuznetsov, V. V.
AU - Khakimov, Dmitry
AU - Dmitrenok, A S
AU - Goloveshkin, Alexander S.
PY - 2022
DA - 2022/12/01
PB - Elsevier
SP - 133856
VL - 1269
SN - 0022-2860
SN - 1872-8014
ER -
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@article{2022_Kuznetsov,
author = {V. V. Kuznetsov and Dmitry Khakimov and A S Dmitrenok and Alexander S. Goloveshkin},
title = {Synthesis, structure and peculiarity of conformational behavior of 1,5-diazabicyclo[3.1.0]hexanes},
journal = {Journal of Molecular Structure},
year = {2022},
volume = {1269},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.molstruc.2022.133856},
pages = {133856},
doi = {10.1016/j.molstruc.2022.133856}
}