Polyhedron

, volume 26 , issue 16 , pages 4620-4624

Photochemical and pharmacological aspects of nitric oxide release from some nitrosyl ruthenium complexes entrapped in sol–gel and silicone matrices

Renata G. Lima ¹

Marília Gama Sauaia ¹

Camila Ferezin ²

Iuri Muniz Pepe ³

Nadia Mamede José ⁴

Lusiane M. Bendhack ²

Zênis Novais da Rocha ⁴

Roberto Da Silva ^{1, 5}

Hide authors affiliations Show authors affiliations: 5 affiliations

Departamento de Quı´mica, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Av. dos Bandeirantes 3900, CEP 14040-901 Ribeirão Preto (SP), Brazil |

Faculdade de Ciências Farmacêuticas de Ribeirão Preto–Universidade de São Paulo, Av. do Café s/n, CEP 14040-903, Ribeirão Preto/SP, Brazil |

Optical Properties Laboratory, LaPO do Instituto de Física da Universidade Federal da Bahia, Campus Ondina, Salvador, Bahia, Brazil |

⁴

Instituto de Química da Universidade Federal da Bahia, Campus Ondina, Salvador, Bahia, Brazil |

⁵

Faculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, Av. do Café s/n, CEP 14040-903 Ribeirão Preto (SP), Brazil |

Publication type: Journal Article

Publication date: 2007-10-01

Elsevier

Polyhedron

scimago Q3

wos Q2

SJR: 0.396

CiteScore: 4.9

Impact factor: 2.6

ISSN: 02775387, 18733719

DOI: 10.1016/j.poly.2007.03.042

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

The entrapped [Ru(terpy)(L)NO](PF 6 ) 3 , where terpy = 2,2′:6′,2″-terpyridine and L = 2,2′-bipyridine (bpy) and 3,4-diiminebenzoic acid (NH · NHq) complexes into sol–gel processed polysiloxane and silicone matrices, shows NO release characteristics when submitted to light irradiation at 355 and 532 nm, as judged by NO measurement using a NO-sensor electrode. The pharmacological properties of doped matrix showed vasodilator characteristics by visible light irradiation, which is of great interest because the target delivery system can avoid the occurrence of side effects possibly by the aquo ruthenium species. All matrices obtained showed to be amorphous materials. The scanning electron micrographs of the matrices showed irregularly shaped particles, with a broad size of 1000 μm for both matrices and homogeneous distribution.

Found

1 citation

Kuzmin Alexey

PhD in Physics and Mathematics

94 publications, 950 citations

h-index: 17

Osipyan Institute of Solid State Physics of the Russian Academy of Sciences

1 citation

Gerasimova Tatiana

PhD in Physics and Mathematics

115 publications, 1 752 citations

h-index: 21

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

1 citation

Budnikova Yulia

DSc in Chemistry, professor

260 publications, 4 537 citations, 54 reviews

h-index: 34

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

C-H functionalization

Catalysis

Charge transfer

Chemistry of organoelement compounds

1 citation

Bochkova Olga

PhD in Chemistry

24 publications, 237 citations, 1 review

h-index: 9

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Federal University

Research interests

Biomarkers

Heterogeneous catalysis

Luminescence

Magnetic resonance imaging (MRI)

Silicon Dioxide Nanoparticles

1 citation

Baimuratova Rose

🥼 🤝

PhD in Chemistry

32 publications, 203 citations

h-index: 7

Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

Research interests

Hydrogenation catalysts

MOFs

Metal-organic coordination polymers

Photocatalysis

Synthesis

1 citation

Utenishev Andrey

PhD in Chemistry, associate professor

105 publications, 406 citations

h-index: 10

Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

Research interests

Quantum mechanical calculations

X-ray diffraction analysis

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GOST |

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Lima R. G. et al. Photochemical and pharmacological aspects of nitric oxide release from some nitrosyl ruthenium complexes entrapped in sol–gel and silicone matrices // Polyhedron. 2007. Vol. 26. No. 16. pp. 4620-4624.

GOST all authors (up to 50) Copy

Lima R. G., Sauaia M. G., Ferezin C., Pepe I. M., José N. M., Bendhack L. M., da Rocha Z. N., Da Silva R. Photochemical and pharmacological aspects of nitric oxide release from some nitrosyl ruthenium complexes entrapped in sol–gel and silicone matrices // Polyhedron. 2007. Vol. 26. No. 16. pp. 4620-4624.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.poly.2007.03.042

UR - https://doi.org/10.1016/j.poly.2007.03.042

TI - Photochemical and pharmacological aspects of nitric oxide release from some nitrosyl ruthenium complexes entrapped in sol–gel and silicone matrices

T2 - Polyhedron

AU - Lima, Renata G.

AU - Sauaia, Marília Gama

AU - Ferezin, Camila

AU - Pepe, Iuri Muniz

AU - José, Nadia Mamede

AU - Bendhack, Lusiane M.

AU - da Rocha, Zênis Novais

AU - Da Silva, Roberto

PY - 2007

DA - 2007/10/01

PB - Elsevier

SP - 4620-4624

IS - 16

VL - 26

SN - 0277-5387

SN - 1873-3719

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2007_Lima,

author = {Renata G. Lima and Marília Gama Sauaia and Camila Ferezin and Iuri Muniz Pepe and Nadia Mamede José and Lusiane M. Bendhack and Zênis Novais da Rocha and Roberto Da Silva},

title = {Photochemical and pharmacological aspects of nitric oxide release from some nitrosyl ruthenium complexes entrapped in sol–gel and silicone matrices},

journal = {Polyhedron},

year = {2007},

volume = {26},

publisher = {Elsevier},

month = {oct},

url = {https://doi.org/10.1016/j.poly.2007.03.042},

number = {16},

pages = {4620--4624},

doi = {10.1016/j.poly.2007.03.042}

}

MLA

Cite this

MLA Copy

Lima, Renata G., et al. “Photochemical and pharmacological aspects of nitric oxide release from some nitrosyl ruthenium complexes entrapped in sol–gel and silicone matrices.” Polyhedron, vol. 26, no. 16, Oct. 2007, pp. 4620-4624. https://doi.org/10.1016/j.poly.2007.03.042.

Publisher

Elsevier

Journal

Polyhedron

scimago Q3

wos Q2

SJR

0.396

CiteScore

4.9

Impact factor

2.6

ISSN

02775387 (Print)

18733719