Palladium(II)–rare-earth metal(III) paddlewheel carboxylate complexes: Easy total acetate to pivalate metathesis
Publication type: Journal Article
Publication date: 2009-01-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Bis-paddlewheel heterobimetallic complexes in which palladium(II) is connected to the rare-earth metals(III) [Pd(μ-OOCMe)4Ln(OH2)(μ,η2-OOCMe)]2 × 2HOOCMe (Ln = Nd, Sm, Eu, Yb and Tm) by four acetate bridges were synthesised by the reaction of Pd3(μ-OOCMe)6 with the LnIII acetates. The tetraacetate-bridged complexes were unexpectedly found to be readily transformed by the stoichiometric amount of pivalic acid into the mono-paddlewheel tetrapivalate-bridged analogues in which the paddlewheel structure [Pd(μ-OOCR)4Ln] maintains as established by X-ray crystallography. The role of the intra- and intermolecular H-bonding in these complexes is discussed.
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Metrics
28
Total citations:
28
Citations from 2024:
1
(3%)
The most citing journal
Citations in journal:
7
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GOST
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Kozitsyna N. Y. et al. Palladium(II)–rare-earth metal(III) paddlewheel carboxylate complexes: Easy total acetate to pivalate metathesis // Polyhedron. 2009. Vol. 28. No. 1. pp. 172-180.
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Nefedov S. E., Vargaftik M., Kozitsyna N. Y., Moiseev I. I. Palladium(II)–rare-earth metal(III) paddlewheel carboxylate complexes: Easy total acetate to pivalate metathesis // Polyhedron. 2009. Vol. 28. No. 1. pp. 172-180.
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RIS
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TY - JOUR
DO - 10.1016/j.poly.2008.10.006
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538708005147
TI - Palladium(II)–rare-earth metal(III) paddlewheel carboxylate complexes: Easy total acetate to pivalate metathesis
T2 - Polyhedron
AU - Nefedov, Sergei E
AU - Vargaftik, Michael
AU - Kozitsyna, Natalia Yu.
AU - Moiseev, Ilya I
PY - 2009
DA - 2009/01/01
PB - Elsevier
SP - 172-180
IS - 1
VL - 28
SN - 0277-5387
SN - 1873-3719
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Kozitsyna,
author = {Sergei E Nefedov and Michael Vargaftik and Natalia Yu. Kozitsyna and Ilya I Moiseev},
title = {Palladium(II)–rare-earth metal(III) paddlewheel carboxylate complexes: Easy total acetate to pivalate metathesis},
journal = {Polyhedron},
year = {2009},
volume = {28},
publisher = {Elsevier},
month = {jan},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538708005147},
number = {1},
pages = {172--180},
doi = {10.1016/j.poly.2008.10.006}
}
Cite this
MLA
Copy
Kozitsyna, Natalia Yu., et al. “Palladium(II)–rare-earth metal(III) paddlewheel carboxylate complexes: Easy total acetate to pivalate metathesis.” Polyhedron, vol. 28, no. 1, Jan. 2009, pp. 172-180. https://linkinghub.elsevier.com/retrieve/pii/S0277538708005147.
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