Synthesis, X-ray crystallography and electrochemistry of three novel copper complexes with imidazole-containing hydantoin and thiohydantoins
Publication type: Journal Article
Publication date: 2013-10-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The reactions of imidazolemethylene-substituted thiohydantoins with copper(II) chloride yield three kinds of complexes with different copper coordination mode. Binuclear complexes Cu2(L1-H)2Cl2 (5), Cu2(L2-H)2Cl (6) and polymeric complex [Cu(L2-H)Cl(H2O)]n (7) (L1 = (4Z)-2-thioxo-4-[(1-methyl-1H-imidazol-2-yl)methylene]-1-allylimidazol-5(4H)-one, L2 = (4Z)-2-thioxo-4-[(1-methyl-1H-imidazol-2-yl)methylene]-1-(n-propyl)imidazol-5(4H)-one) were synthesized and characterized by X-ray diffraction, IR and UV–Vis spectroscopy, and cyclic voltammetry. The crystal structures of homovalent dicopper(II,II) complex 5, mixed-valence [Cu+1.5, Cu+1.5] complex 6 and polymeric copper(II) complex 7 were refined from X-ray powder and single crystal data. Complexes 5–7 undergo eight-step quasi-reversible electrochemical reduction at +0.42 to −2.23 V to stable intermediates, which do not dissociate into free ligand and metal in the conditions of cyclic voltammetry experiments.
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Beloglazkina E. K. et al. Synthesis, X-ray crystallography and electrochemistry of three novel copper complexes with imidazole-containing hydantoin and thiohydantoins // Polyhedron. 2013. Vol. 63. pp. 15-20.
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Beloglazkina E. K., Majouga A. G., Mironov A. V., Yudina A. V., Moiseeva A. A., Lebedeva M. A., Khlobystov A. N., Zyk N. V. Synthesis, X-ray crystallography and electrochemistry of three novel copper complexes with imidazole-containing hydantoin and thiohydantoins // Polyhedron. 2013. Vol. 63. pp. 15-20.
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TY - JOUR
DO - 10.1016/j.poly.2013.07.014
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538713005391
TI - Synthesis, X-ray crystallography and electrochemistry of three novel copper complexes with imidazole-containing hydantoin and thiohydantoins
T2 - Polyhedron
AU - Beloglazkina, Elena K.
AU - Majouga, Alexander G.
AU - Mironov, Andrei V.
AU - Yudina, Anna V
AU - Moiseeva, Anna A.
AU - Lebedeva, Maria A.
AU - Khlobystov, Andrei N
AU - Zyk, Nikolai V.
PY - 2013
DA - 2013/10/01
PB - Elsevier
SP - 15-20
VL - 63
SN - 0277-5387
SN - 1873-3719
ER -
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@article{2013_Beloglazkina,
author = {Elena K. Beloglazkina and Alexander G. Majouga and Andrei V. Mironov and Anna V Yudina and Anna A. Moiseeva and Maria A. Lebedeva and Andrei N Khlobystov and Nikolai V. Zyk},
title = {Synthesis, X-ray crystallography and electrochemistry of three novel copper complexes with imidazole-containing hydantoin and thiohydantoins},
journal = {Polyhedron},
year = {2013},
volume = {63},
publisher = {Elsevier},
month = {oct},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538713005391},
pages = {15--20},
doi = {10.1016/j.poly.2013.07.014}
}