Structure and tuneable luminescence in polymeric zinc compounds based on 3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole
Alexey A. Gusev
1
,
Elena Braga
1
,
Glib Baryshnikov
4
,
Artem V. Kuklin
5, 6
,
B. F. Minaev
3
,
Hans Ågren
6, 7
,
3
Department of Chemistry and Nanomaterials Science, Bohdan Khmelnytsky National University, 18031 Cherkasy, Ukraine
|
7
Publication type: Journal Article
Publication date: 2020-11-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Inorganic–organic hybrid polymers based on 3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole (3,4-Hbpt) ligand were synthesized and subsequently characterized by single-crystal X-ray diffraction, FT–IR spectra, elemental analyses, thermogravimetric (TG) analyses and PXRD. The X-ray diffraction analyses revealed that the complexes [Zn(3,4-Hbpt)Cl2] and [Zn(3,4-Hbpt)Br2] possess a 1-D helical chain structure constructed of the 3,4-Hbpt ligands connecting the zinc cations. The [Zn(3,4-bpt)(OAc)] complex demonstrates a 2D sheet structure bridged by tridentate 3,4-bpt-anions. All compounds exhibit substantial thermal stability and show photo-fluorescent properties that result from the ligand π–π* transition. Ultraviolet-to-visible tunable emission for two of the complexes is observed
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Gusev A. A. et al. Structure and tuneable luminescence in polymeric zinc compounds based on 3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole // Polyhedron. 2020. Vol. 191. p. 114768.
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Gusev A. A., Braga E., Efimov N. N., Kiskin M. A., Kryukova M. A., Karaush-Karmazin N., Baryshnikov G., Kuklin A. V., Minaev B. F., Ågren H., Linert W. Structure and tuneable luminescence in polymeric zinc compounds based on 3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole // Polyhedron. 2020. Vol. 191. p. 114768.
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TY - JOUR
DO - 10.1016/j.poly.2020.114768
UR - https://doi.org/10.1016/j.poly.2020.114768
TI - Structure and tuneable luminescence in polymeric zinc compounds based on 3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole
T2 - Polyhedron
AU - Gusev, Alexey A.
AU - Braga, Elena
AU - Efimov, Nikolay N.
AU - Kiskin, Mikhail A.
AU - Kryukova, Mariya A
AU - Karaush-Karmazin, Nataliya
AU - Baryshnikov, Glib
AU - Kuklin, Artem V.
AU - Minaev, B. F.
AU - Ågren, Hans
AU - Linert, Wolfgang
PY - 2020
DA - 2020/11/01
PB - Elsevier
SP - 114768
VL - 191
SN - 0277-5387
SN - 1873-3719
ER -
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BibTex (up to 50 authors)
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@article{2020_Gusev,
author = {Alexey A. Gusev and Elena Braga and Nikolay N. Efimov and Mikhail A. Kiskin and Mariya A Kryukova and Nataliya Karaush-Karmazin and Glib Baryshnikov and Artem V. Kuklin and B. F. Minaev and Hans Ågren and Wolfgang Linert},
title = {Structure and tuneable luminescence in polymeric zinc compounds based on 3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole},
journal = {Polyhedron},
year = {2020},
volume = {191},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.poly.2020.114768},
pages = {114768},
doi = {10.1016/j.poly.2020.114768}
}