Polyhedron, volume 225, pages 115998
Structurally similar mixed-valent coordination compounds formed during the interaction of bis-5-pyridylmethylene-2-thioimidazolone with CuBr2 и CuCl2
Finko A V
1, 2
,
Guk Dmitry A.
2
,
Saakian Arevik S
2
,
Moiseeva Anna A.
2
,
Тафеенко В. А.
2
,
Pergushov Vladimir I
2
,
Komlev Aleksei S
3
,
Beloglazkin Andrei A
1, 2
,
Borisov Roman S.
1
,
Zyk N. V.
2
,
Majouga Alexander G.
2, 4, 5
,
4
National University of Science and Technology, Leninskii pr., 4, Moscow 119049, Russian Federation
|
Publication type: Journal Article
Publication date: 2022-10-01
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A novel mixed-valent binuclear copper (I/II) coordination compound was obtained by interaction of (5Z,5′Z)-2,2′-(ethane-1,2-diylbis(sulfanediyl))bis(3-allyl-5-(pyridin-2-ylmethylene)-3,5-dihydro-4H-imidazol-4-one) with CuBr 2 in n -BuOH. A structural comparison of this compound with a similar complex obtained in the reaction of the same ligand with CuCl 2 shows that the complex structure-determining role belongs primarily to the ligand rather than the anion of the initial inorganic salt.
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
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Finko A. V. et al. Structurally similar mixed-valent coordination compounds formed during the interaction of bis-5-pyridylmethylene-2-thioimidazolone with CuBr2 и CuCl2 // Polyhedron. 2022. Vol. 225. p. 115998.
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Finko A. V., Guk D. A., Saakian A. S., Moiseeva A. A., Тафеенко В. А., Shiryaeva E. S., Pergushov V. I., Melnikov M. Y., Komlev A. S., Beloglazkin A. A., Borisov R. S., Zyk N. V., Majouga A. G., Beloglazkina E. K. Structurally similar mixed-valent coordination compounds formed during the interaction of bis-5-pyridylmethylene-2-thioimidazolone with CuBr2 и CuCl2 // Polyhedron. 2022. Vol. 225. p. 115998.
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TY - JOUR
DO - 10.1016/j.poly.2022.115998
UR - https://doi.org/10.1016%2Fj.poly.2022.115998
TI - Structurally similar mixed-valent coordination compounds formed during the interaction of bis-5-pyridylmethylene-2-thioimidazolone with CuBr2 и CuCl2
T2 - Polyhedron
AU - Finko, A V
AU - Guk, Dmitry A.
AU - Saakian, Arevik S
AU - Moiseeva, Anna A.
AU - Тафеенко, В. А.
AU - Shiryaeva, Ekaterina S
AU - Pergushov, Vladimir I
AU - Melnikov, Mikhail Y.
AU - Komlev, Aleksei S
AU - Beloglazkin, Andrei A
AU - Borisov, Roman S.
AU - Zyk, N. V.
AU - Majouga, Alexander G.
AU - Beloglazkina, Elena K.
PY - 2022
DA - 2022/10/01 00:00:00
PB - Elsevier
SP - 115998
VL - 225
SN - 0277-5387
ER -
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@article{2022_Finko,
author = {A V Finko and Dmitry A. Guk and Arevik S Saakian and Anna A. Moiseeva and В. А. Тафеенко and Ekaterina S Shiryaeva and Vladimir I Pergushov and Mikhail Y. Melnikov and Aleksei S Komlev and Andrei A Beloglazkin and Roman S. Borisov and N. V. Zyk and Alexander G. Majouga and Elena K. Beloglazkina},
title = {Structurally similar mixed-valent coordination compounds formed during the interaction of bis-5-pyridylmethylene-2-thioimidazolone with CuBr2 и CuCl2},
journal = {Polyhedron},
year = {2022},
volume = {225},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016%2Fj.poly.2022.115998},
pages = {115998},
doi = {10.1016/j.poly.2022.115998}
}