Complexation of 16-membered P4N2 macrocycles with Fe(II) ion as tool for stabilization of their RSSR stereoisomers
Publication type: Journal Article
Publication date: 2022-10-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The only R P S P S P R P -isomer of Fe(II) complex with P 4 N 2 ligand is formed by complexation of any stereoisomer of 16-membered aminomethylphosphine with Fe(BF 4 ) 2. The novel mononuclear Fe(II) complexes of 16-membered P 4 N 2 ligands were synthesized, where octahedral Fe(II) ion is coordinated by four phosphorus atoms of the ligand in equatorial positions and nitrogen atoms of two acetonitrile co-ligands in apical positions. The tetraphosphine ligands demonstrate the R P S P S P R P -configuration regardless of the configuration of the starting stereoisomer of the macrocycles, so that the complexation with iron(II) salts drives up the fixation of this configuration of 1,9-di(R)-1,9-diaza-3,7,11,15-tetraphenyl-3,7,11,15-tetraphosphacyclohexadecanes, which in turn is favorable for the binding of octahedral metal cations.
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Musina E. et al. Complexation of 16-membered P4N2 macrocycles with Fe(II) ion as tool for stabilization of their RSSR stereoisomers // Polyhedron. 2022. Vol. 225. p. 116053.
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Musina E. Complexation of 16-membered P4N2 macrocycles with Fe(II) ion as tool for stabilization of their RSSR stereoisomers // Polyhedron. 2022. Vol. 225. p. 116053.
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TY - JOUR
DO - 10.1016/j.poly.2022.116053
UR - https://linkinghub.elsevier.com/retrieve/pii/S0277538722004053
TI - Complexation of 16-membered P4N2 macrocycles with Fe(II) ion as tool for stabilization of their RSSR stereoisomers
T2 - Polyhedron
AU - Musina, Elvira
PY - 2022
DA - 2022/10/01
PB - Elsevier
SP - 116053
VL - 225
SN - 0277-5387
SN - 1873-3719
ER -
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@article{2022_Musina,
author = {Elvira Musina},
title = {Complexation of 16-membered P4N2 macrocycles with Fe(II) ion as tool for stabilization of their RSSR stereoisomers},
journal = {Polyhedron},
year = {2022},
volume = {225},
publisher = {Elsevier},
month = {oct},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0277538722004053},
pages = {116053},
doi = {10.1016/j.poly.2022.116053}
}