Polymer, volume 212, pages 123299

A microwave-triggered opening of the multifunctional polyelectrolyte capsules with nanodiamonds in the shell composition

Borodina Tatiana 1, 2
Yurina Daria 3
Sokovikov Andrey 3
Karimov Denis N. 3
Bukreeva Tatiana 1, 4
Publication typeJournal Article
Publication date2021-01-01
Journal: Polymer
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor4.6
ISSN00323861
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
Microcapsules are ideal cargo platform for variety of applications such as drug delivery, sensing and imaging due to the combination of a simplicity fabrication and flexibility in the design. We developed remotely collapsing polymer capsules to response to external microwave treatment. The multilayer structure of the capsules was designed to create a polyfunctional system intercalating with nanodiamonds (NDs) and upconversion nanoparticles (UCNPs) into the polyelectrolyte shell. NDs empower local overheating to the microcapsules, while UCNPs provide opportunity to luminescent thermal sensing. UCNPs consist of inorganic crystalline host matrix - hexagonal β-phase NaYF4, doped with pairs of trivalent lanthanide ions, which play role of sensitizer (Yb3+) and activator (Er3+). The microwave triggering followed by the capsule heating results in the controlled destruction of the polyelectrolyte shell with subsequent cargo release. UCNPs luminescence was utilized to determine the local temperature of the capsule shell at nanoscale under GHz ultrasonic treatment. Our novel approach provides on demand microcapsule system destruction, which can be used in the development of nanotheranostic platform for the unification of diagnosis and treatment of various diseases.

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Borodina T. et al. A microwave-triggered opening of the multifunctional polyelectrolyte capsules with nanodiamonds in the shell composition // Polymer. 2021. Vol. 212. p. 123299.
GOST all authors (up to 50) Copy
Borodina T., Yurina D., Sokovikov A., Karimov D. N., Bukreeva T., Khaydukov E. V., Shchukin D. A microwave-triggered opening of the multifunctional polyelectrolyte capsules with nanodiamonds in the shell composition // Polymer. 2021. Vol. 212. p. 123299.
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RIS Copy
TY - JOUR
DO - 10.1016/j.polymer.2020.123299
UR - https://doi.org/10.1016%2Fj.polymer.2020.123299
TI - A microwave-triggered opening of the multifunctional polyelectrolyte capsules with nanodiamonds in the shell composition
T2 - Polymer
AU - Borodina, Tatiana
AU - Yurina, Daria
AU - Sokovikov, Andrey
AU - Karimov, Denis N.
AU - Bukreeva, Tatiana
AU - Khaydukov, Evgeny V.
AU - Shchukin, Dmitry
PY - 2021
DA - 2021/01/01 00:00:00
PB - Elsevier
SP - 123299
VL - 212
SN - 0032-3861
ER -
BibTex
Cite this
BibTex Copy
@article{2021_Borodina,
author = {Tatiana Borodina and Daria Yurina and Andrey Sokovikov and Denis N. Karimov and Tatiana Bukreeva and Evgeny V. Khaydukov and Dmitry Shchukin},
title = {A microwave-triggered opening of the multifunctional polyelectrolyte capsules with nanodiamonds in the shell composition},
journal = {Polymer},
year = {2021},
volume = {212},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.polymer.2020.123299},
pages = {123299},
doi = {10.1016/j.polymer.2020.123299}
}
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