том 113 страницы 84-90

Carrying Agent Influence on the Ruthenium Catalyst Activity of the Ammonia Synthesis

N S Smirnova 1
V. A. Borisov 2
K N Iost 1
V L Temerev 1
Ju V Surovikin 1
T I Guljaeva 1
A. B. ARBUZOV 1
P G Cyrulnikov 1
Тип публикацииJournal Article
Дата публикации2015-08-06
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ISSN18777058
Industrial and Manufacturing Engineering
Краткое описание
The paper examined the catalysts of low-temperature ammonia synthesis Ru-Cs/Sibunit in which Sibunit, mesoporous carbon carrying agents, vary considerably in specific surface area and pore volume, but the pore sizes are similar. According to Raman spectroscopy, the Sibunit structures are same. Applied ruthenium dispersiveness, determined by CO chemisorption, are also close (∼ 13 - 16%) for all the examined catalysts. The difference in the activity of the samples is due to the different direct contact probability of the particles of ruthenium and modifier (CsO x ). This probability decreases with increasing specific surface area ( S BEТ Sibunit) that are supposed to cause the decrease of catalyst activity on high-superficial Sibunit in the ammonia synthesis reaction.
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ГОСТ |
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Smirnova N. S. et al. Carrying Agent Influence on the Ruthenium Catalyst Activity of the Ammonia Synthesis // Procedia Engineering. 2015. Vol. 113. pp. 84-90.
ГОСТ со всеми авторами (до 50) Скопировать
Smirnova N. S., Borisov V. A., Iost K. N., Temerev V. L., Surovikin J. V., Guljaeva T. I., ARBUZOV A. B., Cyrulnikov P. G. Carrying Agent Influence on the Ruthenium Catalyst Activity of the Ammonia Synthesis // Procedia Engineering. 2015. Vol. 113. pp. 84-90.
RIS |
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TY - JOUR
DO - 10.1016/j.proeng.2015.07.296
UR - https://doi.org/10.1016/j.proeng.2015.07.296
TI - Carrying Agent Influence on the Ruthenium Catalyst Activity of the Ammonia Synthesis
T2 - Procedia Engineering
AU - Smirnova, N S
AU - Borisov, V. A.
AU - Iost, K N
AU - Temerev, V L
AU - Surovikin, Ju V
AU - Guljaeva, T I
AU - ARBUZOV, A. B.
AU - Cyrulnikov, P G
PY - 2015
DA - 2015/08/06
PB - Elsevier
SP - 84-90
VL - 113
SN - 1877-7058
ER -
BibTex
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@article{2015_Smirnova,
author = {N S Smirnova and V. A. Borisov and K N Iost and V L Temerev and Ju V Surovikin and T I Guljaeva and A. B. ARBUZOV and P G Cyrulnikov},
title = {Carrying Agent Influence on the Ruthenium Catalyst Activity of the Ammonia Synthesis},
journal = {Procedia Engineering},
year = {2015},
volume = {113},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.proeng.2015.07.296},
pages = {84--90},
doi = {10.1016/j.proeng.2015.07.296}
}