Thermochimica Acta

, volume 659 , pages 113-120

Low-density polyethylene-thymol: Thermal behavior and phase diagram

Konstantin V Pochivalov ¹

Andrey V Basko ¹

Tatyana N Lebedeva ¹

Lyubov A Antina ¹

Roman Yu Golovanov ¹

Vladimir V Artemov ²

А. А. Ежов ^{3, 4}

Yaroslav V. Kudryavtsev ⁴

Hide authors affiliations Show authors affiliations: 4 affiliations

Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya ul. 1, Ivanovo, 153045, Russia |

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics”, Russian Academy of Sciences, Leninsky prosp. 59, Moscow, 119333, Russia

Kurchatov Complex of Crystallography and Photonics of NRC «Kurchatov Institute»

Shubnikov Institute of Crystallography

Faculty of Physics, Lomonosov Moscow State University, Leninskie gory 1-2, Moscow 119991 Russia |

⁴

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia |

Publication type: Journal Article

Publication date: 2018-01-01

Elsevier

Thermochimica Acta

scimago Q2

wos Q2

SJR: 0.640

CiteScore: 6.2

Impact factor: 3.5

ISSN: 00406031, 1872762X

DOI: 10.1016/j.tca.2017.11.012

Copy DOI

Physical and Theoretical Chemistry

Condensed Matter Physics

Instrumentation

Abstract

An experimental full phase diagram for the binary system low-density polyethylene – thymol was for the first time constructed in a broad temperature-concentration range using an original optical method, turbidimetry, and differential scanning calorimetry. Limitations of the two latter techniques were critically analyzed. The diagram belongs to the type semicrystalline polymer – thermodynamically poor solvent so that in the whole concentration range polyethylene and thymol play the role of a solvent and solute, respectively. Thermally induced phase separation leads to the formation of a capillary-porous body. Thymol crystals formed in its pores melt at lower temperatures than crystals from pure thymol solution. The data obtained by different methods can be used for developing the technology of fabricating films with antimicrobial properties.

Found

18 citations

Basko Andrey

PhD in Chemistry

32 publications, 345 citations, 25 reviews

h-index: 11

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

Research interests

Crystallization of polymers

Functional materials

Partially crystalline polymers

Phase equilibria

Physics of polymers

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GOST Copy

Pochivalov K. V. et al. Low-density polyethylene-thymol: Thermal behavior and phase diagram // Thermochimica Acta. 2018. Vol. 659. pp. 113-120.

GOST all authors (up to 50) Copy

Pochivalov K. V., Basko A. V., Lebedeva T. N., Antina L. A., Golovanov R. Yu., Artemov V. V., Ежов А. А., Kudryavtsev Y. V. Low-density polyethylene-thymol: Thermal behavior and phase diagram // Thermochimica Acta. 2018. Vol. 659. pp. 113-120.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.tca.2017.11.012

UR - https://doi.org/10.1016/j.tca.2017.11.012

TI - Low-density polyethylene-thymol: Thermal behavior and phase diagram

T2 - Thermochimica Acta

AU - Pochivalov, Konstantin V

AU - Basko, Andrey V

AU - Lebedeva, Tatyana N

AU - Antina, Lyubov A

AU - Golovanov, Roman Yu

AU - Artemov, Vladimir V

AU - Ежов, А. А.

AU - Kudryavtsev, Yaroslav V.

PY - 2018

DA - 2018/01/01

PB - Elsevier

SP - 113-120

VL - 659

SN - 0040-6031

SN - 1872-762X

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2018_Pochivalov,

author = {Konstantin V Pochivalov and Andrey V Basko and Tatyana N Lebedeva and Lyubov A Antina and Roman Yu Golovanov and Vladimir V Artemov and А. А. Ежов and Yaroslav V. Kudryavtsev},

title = {Low-density polyethylene-thymol: Thermal behavior and phase diagram},

journal = {Thermochimica Acta},

year = {2018},

volume = {659},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.tca.2017.11.012},

pages = {113--120},

doi = {10.1016/j.tca.2017.11.012}

}

Publisher

Elsevier

Journal

Thermochimica Acta

scimago Q2

wos Q2

SJR

0.640

CiteScore

6.2

Impact factor

3.5

ISSN

00406031 (Print)

1872762X (Electronic)

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