, volume 75 , issue 18 , pages 2676-2686

Phosphine-catalyzed bishydrophosphorylation of electron-deficient alkynes

Alexey V. Salin ¹

Anton V Ilin ¹

Rustem I Faskhutdinov ¹

R. А. Fayzullin ²

Hide authors affiliations Show authors affiliations: 2 affiliations

A.M. Butlerov Institute of Chemistry, Kazan Federal University, Kremlevskaya Street 18, Kazan, 420008, Russian Federation. |

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Street, 8, Kazan 420088, Russian Federation

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Publication type: Journal Article

Publication date: 2019-05-01

Elsevier

Tetrahedron

scimago Q3

wos Q2

SJR: 0.426

CiteScore: 4.1

Impact factor: 2.2

ISSN: 00404020, 14645416

DOI: 10.1016/j.tet.2019.03.042

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Organic Chemistry

Drug Discovery

Biochemistry

Abstract

Tertiary phosphines (n-Bu3P, Ph3P) efficiently catalyze the vicinal bis-addition of dialkyl phosphites and diaryl phosphine oxides to alkynoates though the tandem α-umpolung/β-Michael addition. This reaction offers a simple metal-free method for gram-scale preparation of practically useful bisphosphonates and bisphosphine oxides under mild conditions with high atom economy and selectivity.

Found

5 citations

Islamov Daut

PhD

168 publications, 1 577 citations

h-index: 20

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

X-ray diffraction analysis

1 citation

Khannanov Arthur

PhD in Chemistry

53 publications, 820 citations, 46 reviews

h-index: 15

Kazan Federal University

1 citation

Romanov Semyon

PhD in Chemistry

22 publications, 95 citations

h-index: 6

Kazan Federal University

Research interests

Crystal Chemistry

Organoelement chemistry

Organophosphorus chemistry

Pharmaceutical Chemistry

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GOST |

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GOST Copy

Salin A. V. et al. Phosphine-catalyzed bishydrophosphorylation of electron-deficient alkynes // Tetrahedron. 2019. Vol. 75. No. 18. pp. 2676-2686.

GOST all authors (up to 50) Copy

Salin A. V., Ilin A. V., Faskhutdinov R. I., Fayzullin R. А. Phosphine-catalyzed bishydrophosphorylation of electron-deficient alkynes // Tetrahedron. 2019. Vol. 75. No. 18. pp. 2676-2686.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.tet.2019.03.042

UR - https://doi.org/10.1016/j.tet.2019.03.042

TI - Phosphine-catalyzed bishydrophosphorylation of electron-deficient alkynes

T2 - Tetrahedron

AU - Salin, Alexey V.

AU - Ilin, Anton V

AU - Faskhutdinov, Rustem I

AU - Fayzullin, R. А.

PY - 2019

DA - 2019/05/01

PB - Elsevier

SP - 2676-2686

IS - 18

VL - 75

SN - 0040-4020

SN - 1464-5416

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Salin,

author = {Alexey V. Salin and Anton V Ilin and Rustem I Faskhutdinov and R. А. Fayzullin},

title = {Phosphine-catalyzed bishydrophosphorylation of electron-deficient alkynes},

journal = {Tetrahedron},

year = {2019},

volume = {75},

publisher = {Elsevier},

month = {may},

url = {https://doi.org/10.1016/j.tet.2019.03.042},

number = {18},

pages = {2676--2686},

doi = {10.1016/j.tet.2019.03.042}

}

MLA

Cite this

MLA Copy

Salin, Alexey V., et al. “Phosphine-catalyzed bishydrophosphorylation of electron-deficient alkynes.” Tetrahedron, vol. 75, no. 18, May. 2019, pp. 2676-2686. https://doi.org/10.1016/j.tet.2019.03.042.

Publisher

Elsevier

Journal

Tetrahedron

scimago Q3

wos Q2

SJR

0.426

CiteScore

4.1

Impact factor

2.2

ISSN

00404020 (Print)

14645416 (Electronic)

Profiles

Robert R Fayzullin