Stereoselective synthesis of functionalised cyclopropanes from nitroalkenes via an organocatalysed Michael-initiated ring-closure approach
Publication type: Journal Article
Publication date: 2010-05-05
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Synthetically useful nitrocyclopropanes are easily obtained via Michael addition of dimethyl bromomalonate to nitrostyrenes promoted by commercially available (S)-α,α-di-β-naphthlyl-2-pyrrolidinemethanol as the catalyst, followed by DABCO-mediated intramolecular nucleophilic substitution. The functionalised nitrocyclopropanes are obtained in good yield, excellent diastereoselectivity and up to 49% ee.
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28
Total citations:
28
Citations from 2025:
2
(7.14%)
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GOST
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Russo A., Lattanzi A. Stereoselective synthesis of functionalised cyclopropanes from nitroalkenes via an organocatalysed Michael-initiated ring-closure approach // Tetrahedron Asymmetry. 2010. Vol. 21. No. 9-10. pp. 1155-1157.
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Russo A., Lattanzi A. Stereoselective synthesis of functionalised cyclopropanes from nitroalkenes via an organocatalysed Michael-initiated ring-closure approach // Tetrahedron Asymmetry. 2010. Vol. 21. No. 9-10. pp. 1155-1157.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.tetasy.2010.04.005
UR - https://linkinghub.elsevier.com/retrieve/pii/S0957416610002235
TI - Stereoselective synthesis of functionalised cyclopropanes from nitroalkenes via an organocatalysed Michael-initiated ring-closure approach
T2 - Tetrahedron Asymmetry
AU - Russo, Alessio
AU - Lattanzi, Alessandra
PY - 2010
DA - 2010/05/05
PB - Elsevier
SP - 1155-1157
IS - 9-10
VL - 21
SN - 0957-4166
SN - 1362-511X
ER -
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BibTex (up to 50 authors)
Copy
@article{2010_Russo,
author = {Alessio Russo and Alessandra Lattanzi},
title = {Stereoselective synthesis of functionalised cyclopropanes from nitroalkenes via an organocatalysed Michael-initiated ring-closure approach},
journal = {Tetrahedron Asymmetry},
year = {2010},
volume = {21},
publisher = {Elsevier},
month = {may},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0957416610002235},
number = {9-10},
pages = {1155--1157},
doi = {10.1016/j.tetasy.2010.04.005}
}
Cite this
MLA
Copy
Russo, Alessio, and Alessandra Lattanzi. “Stereoselective synthesis of functionalised cyclopropanes from nitroalkenes via an organocatalysed Michael-initiated ring-closure approach.” Tetrahedron Asymmetry, vol. 21, no. 9-10, May. 2010, pp. 1155-1157. https://linkinghub.elsevier.com/retrieve/pii/S0957416610002235.