Establishment of absolute stereostructure of falcarindiol, algicidal principle against Heterocapsa circularisquama from Notopterygii Rhizoma
Тип публикации: Journal Article
Дата публикации: 2010-03-01
SCImago Q3
WOS Q3
БС2
SJR: 0.285
CiteScore: 2.8
Impact factor: 1.4
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Краткое описание
Falcarindiol (1) was isolated as an algicidal principle against the harmful red tide dinoflagellate, Heterocapsa circularisquama, from Notopterygii Rhizoma through bioassay-guided separation. In order to determine the ambiguous absolute structure of this active principle, all three stereoisomers as well as falcarindiol (1) were synthesized. As a result of intensive analysis of their physicochemical properties, the configuration of 1 was revealed to be 3R,8S. On the other hand, (3S,8S)- and (3S,8R)-isomers were found to exhibit more potent algicidal activity than (3R,8S)-falcarindiol (1) isolated from Notopterygii Rhizoma. In addition, the diyne moiety of 1 was established as the crucial structural requirement for algicidal potency.
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ГОСТ
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TAMURA S. et al. Establishment of absolute stereostructure of falcarindiol, algicidal principle against Heterocapsa circularisquama from Notopterygii Rhizoma // Tetrahedron Letters. 2010. Vol. 51. No. 11. pp. 1523-1525.
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TAMURA S., Ohno T., Hattori Y., Murakami N. Establishment of absolute stereostructure of falcarindiol, algicidal principle against Heterocapsa circularisquama from Notopterygii Rhizoma // Tetrahedron Letters. 2010. Vol. 51. No. 11. pp. 1523-1525.
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TY - JOUR
DO - 10.1016/j.tetlet.2010.01.047
UR - https://doi.org/10.1016/j.tetlet.2010.01.047
TI - Establishment of absolute stereostructure of falcarindiol, algicidal principle against Heterocapsa circularisquama from Notopterygii Rhizoma
T2 - Tetrahedron Letters
AU - TAMURA, Satoru
AU - Ohno, Tomomichi
AU - Hattori, Yuuhi
AU - Murakami, Nobutoshi
PY - 2010
DA - 2010/03/01
PB - Elsevier
SP - 1523-1525
IS - 11
VL - 51
SN - 0040-4039
SN - 1873-3581
ER -
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@article{2010_TAMURA,
author = {Satoru TAMURA and Tomomichi Ohno and Yuuhi Hattori and Nobutoshi Murakami},
title = {Establishment of absolute stereostructure of falcarindiol, algicidal principle against Heterocapsa circularisquama from Notopterygii Rhizoma},
journal = {Tetrahedron Letters},
year = {2010},
volume = {51},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.tetlet.2010.01.047},
number = {11},
pages = {1523--1525},
doi = {10.1016/j.tetlet.2010.01.047}
}
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MLA
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TAMURA, Satoru, et al. “Establishment of absolute stereostructure of falcarindiol, algicidal principle against Heterocapsa circularisquama from Notopterygii Rhizoma.” Tetrahedron Letters, vol. 51, no. 11, Mar. 2010, pp. 1523-1525. https://doi.org/10.1016/j.tetlet.2010.01.047.
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