Enantioselective synthesis of nitrocyclopropanes via conjugate addition of bromomalonate to nitroalkenes catalyzed by Ni(II) complexes
Publication type: Journal Article
Publication date: 2012-07-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
A novel one-pot methodology for the catalytic enantioselective synthesis of highly functionalized nitrocyclopropanes promoted by chiral nickel complexes is developed. The treatment of bromomalonates with nitroalkenes under the mild reaction conditions afforded the corresponding Michael adducts which cyclizes to controlled reaction conditions with excellent diasteroselectivities (>99 de) and enantioselectivities (up to 99% ee).
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57
Total citations:
57
Citations from 2025:
3
(5.26%)
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GOST
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Lee H. S., Kim S. H., Kim D. H. Enantioselective synthesis of nitrocyclopropanes via conjugate addition of bromomalonate to nitroalkenes catalyzed by Ni(II) complexes // Tetrahedron Letters. 2012. Vol. 53. No. 27. pp. 3437-3439.
GOST all authors (up to 50)
Copy
Lee H. S., Kim S. H., Kim D. H. Enantioselective synthesis of nitrocyclopropanes via conjugate addition of bromomalonate to nitroalkenes catalyzed by Ni(II) complexes // Tetrahedron Letters. 2012. Vol. 53. No. 27. pp. 3437-3439.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.tetlet.2012.04.072
UR - https://linkinghub.elsevier.com/retrieve/pii/S0040403912006697
TI - Enantioselective synthesis of nitrocyclopropanes via conjugate addition of bromomalonate to nitroalkenes catalyzed by Ni(II) complexes
T2 - Tetrahedron Letters
AU - Lee, Hyun Suk
AU - Kim, Sun Hee
AU - Kim, D H
PY - 2012
DA - 2012/07/01
PB - Elsevier
SP - 3437-3439
IS - 27
VL - 53
SN - 0040-4039
SN - 1873-3581
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Lee,
author = {Hyun Suk Lee and Sun Hee Kim and D H Kim},
title = {Enantioselective synthesis of nitrocyclopropanes via conjugate addition of bromomalonate to nitroalkenes catalyzed by Ni(II) complexes},
journal = {Tetrahedron Letters},
year = {2012},
volume = {53},
publisher = {Elsevier},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0040403912006697},
number = {27},
pages = {3437--3439},
doi = {10.1016/j.tetlet.2012.04.072}
}
Cite this
MLA
Copy
Lee, Hyun Suk, et al. “Enantioselective synthesis of nitrocyclopropanes via conjugate addition of bromomalonate to nitroalkenes catalyzed by Ni(II) complexes.” Tetrahedron Letters, vol. 53, no. 27, Jul. 2012, pp. 3437-3439. https://linkinghub.elsevier.com/retrieve/pii/S0040403912006697.